This research details laboratory assessment of bacterial hydrophobicity, variations in bacterial adhesion properties with growth and extended starvation as well as extension of this assay to colloidal hydrophobicity measurement. Hydrophobicity is an integral component of surface interactions and has been studied extensively for its role in a number of engineering...
Nickel or nickel alloys are common materials used in under bump metallization (UBM) in flip chip technology. Nickel is used because of its slow reaction rate with tin-based solder at
elevated temperatures. However, nickel is ferromagnetic at room temperature, hence cannot be easily deposited with magnetron sputtering. In this study,...
There has been much controversy in recent years over the leaching of chemicals from plastic water bottles. In this study, two of the most common plastics used in water bottles, polyethylene terphthalate (PETE) and polycarbonate (PC) were studied. The leaching of the chemical bisphenol-A (BPA) from polycarbonate (Nalgene ™, Camelback...
The conventional advection-dispersion equation cannot adequately describe all processes driving
solute transport in heterogeneous systems. This dissertation focuses on the individual influences
of both chemical (Chapter 2) and physical processes (Chapters 3 and 4) which affect
solute transport. In Chapter 2 we analyzed uranium transport in natural sediment using the...
Recent advances in nanocrystalline materials production are expected to impact the development of next generation low-cost and/or high efficiency solar cells. For example, semiconductor nanocrystal inks are used to lower the fabrication cost of the absorber layers of the solar cells. In addition, some quantum confined nanocrystals display electron-hole pair...
There is significant interest in utilizing microalgae as a source for biofuels. Diatoms are a class of single-celled microalgae which make silica cell walls and require dissolved silicon as a substrate for cell division. Manipulation of soluble silicon delivery to the culture offers a route to control cell cycle and...
Currently, the technologies used to separate lignocellulosic biomass into its component parts (cellulose, hemicellulose, and lignin) and enzymatically hydrolyze the cellulose to glucose for conversion to ethanol could be improved economically and in terms of efficiency. A major impediment to utilizing the biomass is the presence of residual lignin. The...
A direct numerical simulation of advection-diffusion in a sinusoidal tube was
carried out using the commercial finite-volume code STAR-CD. The Reynolds
numbers varied from Re = 0.1 to Re = 14.5. At the larger Reynolds numbers,
steady-state eddies formed in the diverging sections and significantly influenced
the macroscale dispersion. Long...
Microreactors offer high rates of heat transfer able to intensify highly endothermic biomass reforming reactions in supercritical water. In this study, two continuous flow microreactor configurations were used to gasify biomass constituents in supercritical water. The first reactor configuration was a micro diameter stainless steel or Hastelloy tube (508 µm...
Sulfur content in fuel is an increasingly important environmental concern. A
commonly used method for the removal of sulfur bearing species from fuel is
through hydrodesulphurization. However, due to the implementation of Ultra-Low
Diesel Sulfur (ULDS), deeper desulphurization techniques must be explored. In this
study, a single phase oxidative desulphurization...