This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
Background. As part of the nationwide student completion agenda, the Achieving the Dream (ATD) national reform network was established to help community colleges quickly institute sustainable change scaled to impact all students at the institution in a short period of time. Although ATD has been in existence for over a...
Physical experimentation in various scientific and engineering areas continues to be a useful and often necessary approach that is applied in research, development, and for general problem solving. The experimental design process however, is iterative and often involves trial and error. Alternative designs are proposed and evaluated on cost and...
Small Unmanned Aircraft Systems (sUASs) equipped with optical sensors are capableof remotely sensing landscapes and wildlife at spatial and temporal resolutions that werepreviously inaccessible due to technical and budgetary limitations. Conventional remotesensing and photogrammetric workflows can be applied to the resulting high resolution imageryto facilitate new types of scientific inquiry....
A significant number of Unreinforced Masonry (URM) buildings exist in the Pacific Northwest region of the United States of America that is a region of high seismicity, which could be subjected to both crustal and subduction zone earthquakes. The catastrophic and brittle failures associated with URM buildings in the past...
Turbines at wind projects pose a threat to birds and bats flying at altitudes within the rotor swept area. These animals die from colliding with the turbine blades. Estimating mortality, or the total number of bird or bat fatalities at a wind project, is critical to understanding environmental impacts of...
Polycyclic aromatic hydrocarbons (PAHs) are widespread environmental contaminants that occur in complex mixtures. These environmental mixtures can consist of both parent PAHs and their derivatives. Several parent PAHs are known or suspected mutagens and/or carcinogens, and a handful of PAH derivatives are known to be more potent mutagens and/or carcinogens...
Novel donor-typed ternary graphite intercalation compounds (GICs) are synthesized and characterized containing (1) pyrrolidinium cations with DMSO co-intercalates; (2) alkali metal cations with crown ether co-intercalates; and (3) alkali metal cations with polyethylene glycol co-intercalates. Structural and compositional data are obtained for the stable products. A new ether-amine co-intercalate exchange...
Background: Prior research has shown that distance learning courses have higher failure rates at community colleges then equivalent face-to-face to courses. There are a few programs and courses, however, that consistently achieve completion rates as high as or higher than their equivalent face-to-face courses. The research to date has not...
Biological invasions and climate change represent two preeminent threats to ecological communities and biodiversity, altering the distribution and abundance of species, disrupting existing species interactions and forming unprecedented ones, and creating novel ecological communities. Many of the most successful invasive species are also ecosystem engineers, species that physically modify the...
The role of ground motion duration on the seismic performance of civil engineering structures remains unclear. Thus, the role of earthquake strong ground motion duration is assessed in a three manuscript thesis, which includes: (1) assessment of the effects of ground motion duration on the seismic performance of a model...
Mathematical modeling plays a pivotal role in understanding the mechanism of radiation-induced cellular effects, and also in quantifying the radiation risk to the cell. However, there are still compelling challenges facing the conventional modeling in radiobiology, such as lacking a generalized theory structure of quantifying target effect and non-target effect...
Significant progress has been made over the past 20 years in developing models to estimate the service-life of reinforced concrete systems. The basic understandings of the mechanisms that control the transport of ions and moisture in concrete systems have been well researched and models for determining corrosion initiation, specifically chloride-induced...
Transportation systems are facing safety and operational challenges with a cost of billions of dollars annually in lost production time and wasted fuel. Infrastructure expansion, previously held as a panacea to most transportation challenges has lost its appeal due to financial, land-use and environmental constraints. Interest is surging in intelligent...
The first part of this manuscript is about the total synthesis of the Arundo donax bis(indole) natural products. The A. donax alkaloids were prepared using the first example of an ynindole Diels–Alder reaction. Each were then separated, isolated, and determined to have stable enantiomeric conformations at room temperature (Chen, J.;...
Femtosecond stimulated Raman spectroscopy (FSRS) is an ultrafast vibrational technique which allows rapid collection of Raman spectra with simultaneously high temporal and spectral resolution. With the recent development of FSRS methodology, three FSRS techniques (conventional, tunable, and anti-Stokes) have been implemented in our laboratory to dissect the excited state structural...
In the U.S., childhood overweight and obesity has grown to epidemic levels. The National Survey of Children’s Health (NSCH) found that nationwide, approximately 32% of children 10–17 years old are identified as overweight, over half of them (nearly 17%) are obese. This is a concern because these rates continue to...
In this work we will analyze branching Brownian motion on a finite interval with oneabsorbing and one reflecting boundary, having constant drift rate toward the absorbingboundary. Similar processes have been considered by Kesten ([12]), and more recently byHarris, Hesse, and Kyprianou ([11]). The current offering is motivated largely by the...
Relationship health has many benefits, from physical and emotional health of the partners to their children’s wellbeing. Early intervention programs protect relationships from decline. These programs represent growing public health initiatives. However, most studies on wellness or early intervention overlook lesbian and gay male couples. Research that assumes lesbian and...
This dissertation seeks to understand Yi farmers’ livelihoods in the midst of an agricultural transition in Yunnan, Southwest China. This dissertation examines a community’s traditional knowledge related to wild edible plants (WEPs), analyzes socio-ecological vulnerability and resilience in the face of agricultural transition from subsistence farming to cash cropping, and...