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Filtering by: Creator Kirkpatrick, Robynne Decade 2010-2019

Examination of low-lying rovibrational states of D₃[subscript h] oblate top molecules using high resolution FTIR and coherent anti-Stokes Raman spectroscopies

Creator:

Kirkpatrick, Robynne

Abstract:

Interesting rovibrational characteristics of two D_(3h) oblate symmetric top molecules were studied. Hamiltonian models for the fine rovibrational level structure of [1.1.1]propellane (propellane) were obtained for many low-lying modes. Ground state parameters (GSP) that are not exclusively K^(2n) dependent were obtained. Initially, the GSP were used in conjunction with density...

Resource Type:

Dissertation

Full Text:

Robynne Kirkpatrick for the degree of Doctor of Philosophy in Chemistry presented October 15, 2010
High-resolution infrared studies of the ν10, ν11, ν14, and ν18 levels of [1.1.1]propellane

Creator:

Kirkpatrick, Robynne, Masiello, Tony, Martin, Matthew, Nibler, Joseph W., Maki, Arthur, Weber, Alfons, and Blake, Thomas A.

Abstract:

This paper is a continuation of earlier work in which the high resolution infrared spectrum of [1.1.1]propellane was measured and its k and l structure resolved for the first time. Here we present results from an analysis of more than 16,000 transitions involving three fundamental bands v₁₀ (E' - A'₁),...

Resource Type:

Article

Full Text:

, and m18 levels of [1.1.1]propellane Robynne Kirkpatrick a, Tony Masiello b, Matthew Martin a, Joseph