Thermodynamic modeling of cementitious material is an established tool for predicting the hydrated phase assemblages, pore solution pH, and pore solution composition of mixtures of various chemical compositions and water-to-binder (w/b) ratios. However, traditional thermodynamic techniques have major limitations for modeling mixtures containing supplementary cementitious materials (SCM), and when modeling...
This thesis builds on a modeling tool that has been developed to link thermodynamic modeling and concrete performance. This tool is intended to predict the performance for modern concrete mixtures made with ordinary portland cement (OPC), conventional and novel supplementary cementitious materials (SCMs), and limestone (Ls). The first part of...
The most common test methods to evaluate alkali-silica reaction (ASR), the concrete prism test (CPT) and the accelerated mortar bar tests (AMBT), have limitations and are not entirely reliable in terms of predicting the performance of concrete with prevention measures under field conditions. In this study, the miniature concrete prism...
Chloride binding in Portland limestone cements (PLC) can be attributed to the chemical reaction between chloride ions and carboaluminate phases to form Friedel’s salt and the physical interaction between chloride ions and calcium-silicate-hydrates (C-S-H). This thesis examines the chloride binding of mortar samples containing varying amounts of limestone, fly ash,...
The issue of chloride-induced corrosion of reinforcing steel in concrete and its economic impacts are well-known. Chlorides that cause reinforcement corrosion can be from constituent materials used to prepare concrete or can enter the hardened concrete when the structure is exposed to chloride environments. To minimize the risk of reinforcement...