Zinc Sulfide (ZnS) thin film, with a wide band gap, has been used for many applications, such as buffer layer for CIGS solar cells, light emitting diodes and thin film electroluminescent devices.
In this work, ZnS thin films were prepared using two different deposition processes. In the first method, ZnS...
Cognitive radio technology emerges as a promising solution for overcoming shortage and inefficient use of spectrum resources. In cognitive radio networks, secondary users, which are users equipped with cognitive radios, can opportunistically access spectrum assigned to primary users, the spectrum license holders. Although it improves spectrum utilization efficiency, this opportunistic...
This study computationally and experimentally examines the mechanisms of crack penetration, deflection and the transition between penetration and deflection. The finite element analysis based computational modeling work used strength-and-energy based cohesive-zone approach to study the effect of dimensionless parameters (e.g., interfacial incident angle, fracture-length scale, and normalized toughness) on penetration/deflection...
The rapid scaling of network bandwidth and data center throughput has motivated the wide adoption of high speed transceivers. Silicon photonics (Si-Photonic) is one of the most promising techniques to realize tightly integrated optical transceivers for next-generation high speed I O standards. This dissertation focuses on the design techniques of...
The aim of this research is to develop a fundamental understanding of the dominant defect species and the relevant defect equilibrium conditions for bismuth-containing perovskites to help guide the development of these materials for emerging applications. This is of paramount importance for many demanding applications, because ultimately the defect equilibria...
In 2008, the “Great Recession” gained its momentum and quickly grew into a global crisis that led to massive gross domestic product declines and job losses in countries around the world. Relative to prior economic downturns, young adults were greatly affected by the Great Recession. This likely placed a premium...
Over the past two decades, the Lean Construction academic and practicing engineering community has used lean practices and tools to help improve the performance of the Architecture, Engineering, and Construction (AEC) industry. Lean practices have led to improved competitiveness of construction companies that have adopted them, by focusing on ways...
Accumulating human impacts on freshwater ecosystems have created a biodiversity crisis for freshwater fishes while conservation efficacy remains hampered by the Linnaean shortfall, the ignorance of many species that have yet to be discovered and described. The past discovery of most freshwater fish species was simply a matter of collecting...
The research presented in this dissertation focuses on the model generation and modeling processes of student teams that participate in capstone, undergraduate engineering physical and virtual laboratory projects. The Heat Exchange Laboratory Project, the Ion Exchange Laboratory Project, and the Virtual Chemical Vapor Deposition (CVD) Laboratory Project provide the context...
At a time when the biodiversity on Earth is being rapidly lost, new technologies and methods in genomic analysis are fortunately allowing scientists to catalog and explore the diversity that remains more efficiently and precisely. The studies in this dissertation investigate genomic diversity within the milkweed genus, Asclepias, at multiple...
Despite the advance of biomedical science, infectious diseases remain one of the number one killers in the world. They claim the lives of millions of people annually, particularly in underdeveloped and developing countries. In fact, more than 32% of the health burden in Africa is caused by infectious diseases, e.g.,...
Irrigated agriculture constitutes the greatest consumptive water use globally, so that irrigation efficiency measures are an important part of global efforts to best utilize this limited resource. However, greater irrigation efficiency must be achieved while simultaneously maintaining or increasing crop yields and farming profitability. Incremental water use decisions are made...
The multifaceted role of the environment in regulating the structure and dynamics of biological communities has long fascinated ecologists and motivated much debate and research. Now, in a time of accelerated global changes due to human impacts, the need to understand how the environment shapes communities has gained new urgency....
This dissertation explores one overarching question relevant to the
paleoclimate of the latest Pleistocene glacial cycle (approximately the last
130,000 years): “How did spatial and temporal evolution of ocean
temperature, both at the surface and interior, relate to other parts of the
climate system in the late Pleistocene?” Results from...
Thiamine (vitamin B₁) is required by all living organisms for carbohydrate metabolism and synthesis of amino acids. Thiamine deficiency is responsible for several related classes of early life stage mortality disorders in salmonines, including Thiamine Deficiency Complex (TDC) in the Laurentian Great Lakes, Cayuga Syndrome in the Finger Lakes, and...
Intrinsically disordered proteins (IDP) are a class of proteins that lack a three-dimensional structure and their prevalence and diverse functions in the cell have only been discovered relatively recently. The intermediate chain (IC) subunit of the microtubule motor protein complex dynein contains an N-terminal disordered region, N-IC, which is central...
In this thesis, we will study certain generalizations of the classical Shannon Sampling Theorem, which allows for the reconstruction of a pi-band-limited, square-integrable function from its samples on the integers. J. R. Higgins provided a generalization where the integers can be perturbed by less than 1/4, which includes nonuniform and...
The transition of mature pollen to the progamic phase represents an important step in the regulation of plant sexual reproduction. The progamic phase encompasses the initiation of pollen tube germination, growth of the pollen tube through the stigma (the silk in maize) and concludes with fertilization of the female gametophyte....
Three distinct methods to achieve the stereoselective synthesis of carbon-carbon bonds were investigated, encompassing: (i) the formation of axially chiral biaryl molecules by enantioselective Suzuki cross-coupling, (ii) the synthesis of α-phenylalkylboronic esters by enantioselective chain extension, and (iii) the stereospecific synthesis of alkenes by eliminative cross-coupling of enantioenriched sp³-hybridized carbenoids....
Nonparametric model-assisted estimators have been proposed to improve estimates of finite population parameters. More efficient estimators are obtained when the parametric model is misspecified due to the flexibility of nonparametric models. In this dissertation, we derive information criteria to select appropriate auxiliary variables to use in an additive model-assisted method....
With continual and worldwide human population growth, our impact on the natural environment expands and intensifies every day. We consume natural resources, burn fossil fuels, and release toxic compounds into the air, water, and earth. We build roads that fragment the landscape, construct new settlements, and develop agricultural lands in...
More than 1500 species of plants and animals in the United States are listed as threatened or endangered under the Endangered Species Act (ESA). The U.S. Departments of Interior and Commerce are required, under Section 4(f)(1) of the ESA, to develop recovery plans for ESA-listed species under the respective agency...
Multiple Sclerosis (MS) is an autoimmune condition that affects the central nervous system, and impacts the lives of over 400,000 individuals in the US. These individuals face unpredictable relapses of disabling conditions, are less active and experience poorer quality of life than the general population. Health professionals are challenged to...
The promotion of out of school physical activity during physical education has received increasing attention as a tool for combating increasing sedentary time among youth. Qualitative work has shown that physical education teachers feel they lack the knowledge necessary to include physical activity promotion in their lessons and unprepared by...
Hop aroma in beer is related to the unique compositional chemistry of the hops used in the brewing process. While the range of these compositions is quite diverse and primarily dependent on hop cultivar¹, other studies have also shown that cultivation, seasonality, harvesting², processing³⁴, and storage practices⁵⁶ contribute to differences...
This dissertation is an exploration of the material response to Terahertz (THz) radiation. Specifically we will explore the ultrafast electron dynamics in the nonperturbative regime in semiconductors that have been patterned with nanoantenna arrays using broadband, high intensity, THz radiation. Three main semiconductor materials will be studied in this work....
Empirical studies have shown that programmers spend up to one-third of their time navigating through code during debugging. Although researchers have conducted empirical studies to understand programmers’ navigation difficulties and developed tools to address those difficulties, the resulting findings tend to be loosely connected to each other. To address this...
There are many links between exposure to environmental pollution and risks to human health. While advances in the fields of toxicology, exposure science, and environmental chemistry have shown light on many of these links, many more research challenges remain. One major challenge is how to accurately characterize the toxicity of...
Clostridium perfringens type A strains are one of the main causative agents of gastrointestinal (GI) diseases in human and can cause both food poisoning (FP) and non-food-borne (NFB) diseases. Several factors contribute to the pathogenesis of C. perfringens type A strains including the wide presence of C. perfringens spores with...
High counts of fecal indicators, used to signal the potential presence of pathogens associated with untreated waste, result in the classification of water bodies throughout the United States as impaired. Nonpoint sources of unknown origin that contribute to fecal contamination make management of impaired waters challenging, as they are difficult...
This dissertation serves a threefold purpose: 1. identify the principles, practices and assumptions implicated in an academic theory of social justice; 2. continue moving towards articulating a theory of social justice judgment and decision making; and 3. develop a model of social justice judgment and decision making that will assist...
Red clover (Trifolium pratense L.) seed yield can be affected by plant growth regulators (PGR) and irrigation; however, the effects of these factors on physiological maturity (PM), harvest maturity (HM), and seed quality are unknown. The objectives of this study were to: 1) determine how irrigation and trinexapac-ethyl (TE, a...
There is increasing awareness that human activities are altering the ways that natural systems operate and that local shifts in species composition and abundance can lead to abrupt and irreversible global change. Therefore, understanding the processes that buffer biological communities from critical shifts and how our actions affect natural stabilizing...
Background. Autism spectrum disorder (ASD) is characterized by impairments in social-communicative deficits and restricted and repetitive behaviors, interests, or activities (APA, 2013). While current estimates suggest 1 in 68 children are diagnosed with ASD, more alarming statistics indicate 1 in 50 school-aged children live with the disorder (Blumberg, Bramlett, Kogan,...
Passive sampling devices (PSDs) were used to measure air vapor and water dissolved phase concentrations of polycyclic aromatic hydrocarbons (PAHs) and oxygenated PAHs (OPAHs) at two different environmentally contaminated sites. Environmental contaminates like PAHs and OPAHs are present in both the atmospheric and aqueous environmental compartments. It is known that...
This dissertation presents nonlinear terahertz (THz) properties of carbon nanomaterials investigated by time-resolved high-field THz spectroscopy. In order to determine THz characteristics of nanomaterials, we performed THz power spectrum measurement, THz raster imaging, THz time-domain spectroscopy (THz-TDS) and time-resolved pump-probe experiment on two different types of single layer graphene and...
English Language Learners (ELLs) represent a culturally and linguistically diverse population in US schools. ELLs enter kindergarten with a range of academic and self-regulation skills, but can face multiple challenges navigating the school context (Zwiers, 2013). Previous research documents that low-income ELLs lagged behind in academic achievement, self-regulation, and English...
Energy consumption has become a great deal for cloud service providers due to financial as well as environmental concerns. Studies show that cloud servers operate, most of the time, at only between 10% and 50% of their maximal utilizations. These same studies also show that servers that are kept ON...
Brown marmorated stink bug (BMSB), (Halyomorpha halys, Hemiptera: Pentatomidae) is an invasive species that damages numerous agricultural crops including grapes. Related damage include lower berry weight with increased exposure and cracked berries as a result of BMSB feeding activity. The insect is currently detected in 43 US states including Oregon,...
Magnetic thin films have potential to improve devices such as on-chip inductors, and enable new technologies such as magnetic random access memory (MRAM).
The use of magnetic cores in on-chip inductors is typically limited to applications well under 1 GHz. At higher frequencies, the performance of the magnetic core is...
Enantioenriched sp³-hybridized carbenoid reagents CR1R2MX (X = nucleofuge, M = electrofuge) of different types were investigated for the synthesis of polysubstituted alkyl chains by iterative stereospecific reagent-controlled homologation (StReCH) and for the stereospecific connective synthesis of alkenes by eliminative cross-coupling.
In the first part, putative enantioenriched α-chloroalkyllithiums (CHRLiCl) were employed...
The advent of improved DNA sequencing technologies has allowed the analysis of various microbial communities. Bloom-forming freshwater cyanobacteria can produce toxins and taste-and-odor compounds that can negatively affect drinking water supplies. Here, I have employed second- and third-generation sequencing technologies to characterize bloom-forming freshwater cyanobacterial genomes and their associated heterotrophic...
The development of resistance to multiple fungicide classes is currently limiting disease management options for many pathogens, while the discovery of new fungicide classes has become less frequent. To address this pressing issue, a three-part study with different layers of complexity, objectives, and experimental approaches was conducted using the model...
Recent state and national standards have increased the interest in engineering at the K-12 level. Science standards, in particular, have begun to make the case for including engineering throughout the K-12 scope of study. Despite the increased attention to engineering, the characteristics and uniqueness of the field of engineering are...
Moisture content management is a key requirement to improve forest harvest residue economics for bioenergy production. This dissertation aims to contribute towards better management through these three general objectives (1) Determine average moisture content of fresh forest harvest residues and its changes over the different seasons of the year, focusing...
The National Research Council has aggregated research evidence on the pedagogy of science teaching and learning (NRC, 2012), culminating in the Next Generation Science Standards (NGSS). These standards support emphasis on eight scientific practices as an important component for teaching science as inquiry to K-12 students. This latest framework for...
The illicit use of opioids among young adults (18–25) has resulted in an increase of clients needing substance abuse treatment. Treatment programs are struggling to keep up with the influx of these young adults. Traditional models of care have some impact; however, there are not enough treatment centers that can...
This study proposed a theoretical model of choice overload and empirically examined the model in the context of online apparel shopping. The purpose of the study was to investigate how the number of choices and product presentation formats influenced consumers’ online apparel shopping experience as well as how the formed...
The Office of Disease Prevention and Health Promotion released the Healthy People 2020 plan in 2010 (Office of Disease Prevention and Health Promotion [ODPHP], 2010). The mission of Healthy People 2020 is focused on improving the health of all Americans. One common tool utilized to improve the health of Americans...
Differential expression (DE) analysis is a key task in gene expression study, because it uncovers the association between expression levels of a gene and the covariates of interest. This dissertation pertains to two particular aspects of DE analysis—identifying stably expressed genes for count normalization and accounting for correlation between DE...