Steroid organoboranes have been found to be useful synthetic
intermediates. Attempted pyrolyses, based on simple trialkylborane
cyclizations, have not yielded C-19 or C-18 functionalized steroids,
but have produced isomerized systems not otherwise available.
Thus, hydroboration of cholesterol followed by pyrolysis at
215° gives 31% of 2-cholestene-6α-ol and 49% of a...
Diets containing cyclopropenoid fatty acids (CPFA) were fed to
rainbow trout. At a level of 223 ppm (from Sterculia foetida oil),
these CPFA in six weeks reduced weight gain by as much as 50 percent
over the control fish on the same diet without CPFA. Compounds
containing the intact cyclopropene...