As the development, processing, and manufacturing of plastic has improved over the years, so has our amount of plastic waste. Currently, only approximately 9% of post-consumer plastics get recycled. The other 91% is buried in landfills, burned, ends up in the ocean, or is accumulating in communities without access to...
The corrosion and heat resistance properties of nickel alloys are hallmarks of their importance in infrastructure and industrial catalysis processes, but these properties are highly dependent on the chemical composition of the alloy surface. Density functional theory was used for analysis of surface oxidation of four combinations of chromium and...
Nitrate is a toxic surface and ground water contaminant that poses human-health and ecological hazards. Contamination is anthropogenically sourced to over-amendment of ammonia-based fertilizers, in turn generated by the most carbon intensive chemical process in use today. Electrochemical approaches offer a green alternative to transform harmful waste nitrate into value-added...
ZIF-8, a zeolitic imidazolate framework that consists of zinc ions and imidazolate linkers, is of great interest due to its simple synthesis methods, low-cost raw materials, chemical and thermal stability, as well as its stability in moist environments. Furthermore, due to its unique structure, it contains well-defined pores that have...
As a result of the COVID-19 pandemic, most colleges and universities around the world were forced to switch to remote learning. Many instructors were provided little guidance regarding how to restructure their courses for the remote classroom. The purpose of this study was to understand how the shift from in-person...
Water splitting is a green method being researched to produce green hydrogen in order to combat greenhouse gases emitted by the most popular energy source; fossil fuels. Water splitting involves two half reactions: hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Of these two, OER is the bottleneck water...
The anticonvulsant drug carbamazepine (CBZ) is a commonly prescribed drug that is used to treat patients with neurological disorders including epilepsy and bi-polar disorder. CBZ has a narrow range of efficacy: Below the therapeutic dose, seizures and other conditions are not controlled, and above the recommended window, patients experience side...
The detection of biomolecules is critical for clinical diagnostics but requires specialty labor and high cost. The use of microfluidic paper-based analytical devices (µPADs) for bioassays is simpler and cheaper but has low sensitivity. Improved immobilization of antibodies onto cellulose is demonstrated through surface functionalization with APTES and glutaraldehyde. The...
Current natural product (NP) research is limited by its reliance on bioassay-guided fractionation to identify bioactive compounds in mixtures. Computational approaches may improve NP research by correlating mass spectra (MS) and nuclear magnetic resonance spectra (NMR) of bioactive mixtures to their bioactivity patterns. In this study, I use artificial neural...
In this work, a hybrid thermochemistry compressed air energy storage (CAES) system is investigated. Following a review on chemical reactions investigated for use in thermochemical energy storage (TCES) systems, from these chemistries, the conversion of magnesium carbonate, MgCO3, to magnesium oxide, MgO, and carbon dioxide, CO2, was further analyzed for...
Flax fibers are frequently used as a sustainable and recyclable reinforcement for composite materials in aesthetic applications (ex. car interiors). Flax fibers are biodegradable and can be sustainably harvested. Furthermore, the question of how to dispose of flax reinforced materials after the end of their lifetime can be solved in...
Learning assistant (LA) programs are gaining increasing popularity as a means to shift instructional practice in STEM classrooms. In these programs, trained undergraduate students join the instructional team and support student-centered active learning pedagogies. Their professional development is typically supported through a seminar. In facilitating small group collaborative learning, LAs...
Climate change is a pertinent issue causing an increase in the quantity and severity of wildfires. Current market solutions to protect homes from wildfires are expensive and do not always guarantee the safety of the home. Superabsorbent polymer (SAP) is a cross-linked polymer that can absorb over 100x its weight...
Arsenic in its inorganic form is naturally present in groundwater. Continued exposure to arsenic contaminated water can result in long lasting health complications, ranging from cognitive development issues to cancer. One method which may be convertible to a field test is the use of PEG functionalized gold nanoparticles which aggregate...
Recently, there has been an expansion of large-scale studies looking at strain variation of Brettanomyces. These studies have found variation between strains in terms of utilization of maltose and production of volatile phenols. While there is research going into this subject, there is a gap in knowledge regarding the differences...
The goal of this project is to better characterize particle movement in a multi-channel fluidized bed. Fluidized beds are commonly used for heat transfer with the rapid fluidization and homogeneous heat distribution. By characterizing this particle flow, it would allow for an improved understanding of the heat transfer mechanisms within...
Lanthanide (Ln) based molecular complexes have shown great potential as Lewis acid catalysts for the activation of small molecules. Despite the wealth of structural versatility and high catalytic activity of these complexes, they often lack selectivity and recyclability. This hinders their potential for use in large-scale industrial applications where waste...
Solar thermal energy can be stored and later converted to electrical energy using a combination of thermochemical energy storage (TCES) and a thermoelectric generator (TEG). This TEG and TCES combination illustrates a potential route for clean electricity storage from renewable energy. TCES allows for thermal energy from the sun to...
Significant challenges remain before lithium-ion batteries can support the decarbonization of the transportation and power sectors required to avert catastrophic climate change. The energy density of these batteries must be increased, while decreasing the price, and maintaining or increasing their lifespan. To improve the practical energy density of existing materials,...
Water is one of the world’s most valued commodities, and antibiotic-resistant bacteria are one of the emerging pollutants of concern. Stormwater runoff picks up pollutants such as bacteria as it runs over impervious surfaces and into waterbodies. This project tested the use of biochar columns as an effective and inexpensive...
Metal Organic Framework Structures (MOFs) have shown great promise for use in gas storage. Computer simulations have been touted as a method to identify strong candidate molecules for experimental research. This project assessed the relationship between computer simulations of methane absorption and experimental gas absorption. We acquired experimental data and...
To assess the conversion and embedment of yttrium nitrate to yttrium oxide using selective laser melting, a thermodynamic approach for laser power and scan speed predictions on surface temperature, recoil pressure, and resulting track morphology window are employed. Inkjet printing is used to deposit the liquid film of yttrium nitrate...
Microscale-based technology has potential applications in the medical field. The development of a new microscale medical device requires experimentation and testing. This can be done by creating a breadboard device that can perform the functionalities the final device should be able to do. This breadboard device can also be used...
Extending rheological characterization methods to very small length scales is of interest. AC susceptometry using magnetic nanoparticle probes has been proposed for measurement of frequency-dependent rheological properties at the nanoscale. As this technique has been primarily used for ideally Newtonian fluids, this research aimed to extend this technique to viscoelastic...
While hemodialysis is a unique therapy for treating chronic kidney failure, the application of extracorporeal blood processing presents the opportunity for treating a wider range of bloodborne diseases. The objective of the i-Blood research team is to develop a blood processing device that utilizes microscale-based technology as a platform for...
Tracking footwear wear patterns is vital to the footwear industry. In the game of tennis, there are several court surfaces that produce unique wear patterns on footwear that are constantly changing according to the following factors: level of competition, level of experience, coordination, age, height, weight, and more. By tracking...
One of the principal drivers of climate change is the concentration of greenhouse gases such as CO2 in the atmosphere. A large portion of this CO2 ends up in the waters off the continental coasts where it transforms into biomass. The major sink for this matter is the ocean sediments...
Lithium serves an unparalleled role for high energy-density storage applications and is vital for the continued advancement of the world economy. However, global supply is heavily reliant on lithium deposits situated in select locations, creating unpredictability in the price and concerns for the sustained production of the resource. Additionally, future...
Natural freshwater availability is decreasing as the global population increases. Advances in desalination technologies aim to produce fresh water in an economical way. More sustainable energy sources are desired for these desalination plants to limit the carbon footprint of water production since global carbon dioxide production is exacerbating freshwater scarcity....
Cancer is currently the second leading cause of death in the United States and the sixth leading cause of death worldwide. Due to cancer’s variability in type, location, growth rates, and patient physiology, treatment models are based off of previous experimental and clinical work. This variability, however, can lead to...
Molybdenum disulfide (MoS2) has potential applications as a low-cost catalyst for the hydrogen evolution reaction (HER). Defects on MoS2, such as edge sites and sulfur vacancies, are known to be the major active sites for HER. Controlling the formation of these defects allows for the enhancement in reactivity of MoS2...
Concentrated solar power (CSP) along with thermal energy storage (TES) has the potential to provide reliable energy from an intermittent source. TES is used to store energy while the sun is shining, allowing for the stored energy to be used when the sun is no longer shining. There are many...
A present abundance of biomass and a decreasing supply of petroleum signal the need for efficient pathways from renewable feedstocks to high value chemicals. One such class of chemicals is oleofurans, molecules comprised of a furan ring and carbon chain which can be used to make powerful hard water surfactants....
The purpose of this research is to provide a simple fabrication method for zinc oxide and antimony sulfide based thin film solar cells. Both a ZnO nanorod electron conducting structure and a stibnite absorber show promise in a solar cell. Initial attempts at using only ZnO and Sb2S3, however, resulted...
High purity isopropyl alcohol (IPA) is utilized in silicon wafer manufacturing in cleaning and drying processes. With the ever-decreasing die size, there is an increased need for even higher purity chemicals. This process was designed to further purify a 250,000 lbs/month stream high purity isopropyl alcohol stream for use in...
Highly elastic solutions have been shown to increase contaminant removal from silicon wafers, indicating the possibility for reduced reliance upon hazardous chemicals and expensive technologies during the fabrication of semiconductor devices. The onset of this enhanced removal is explored using rinsing and siphoning experimentswith polymer fluids of high molecular weights...
Our society today is heavily dependent on fossil fuels such as coal and oil. However, growing environmental concerns and future fossil fuel supplies have led to interests in alternative fuels. Dimethyl Ether (DME) is an inexpensive, clean-burning, non-toxic, and potentially renewable fuel, making it a suitable choice as an alternative...
The OSU-Benton County Green Stormwater Infrastructure Research (OGSIR) Facility was created to test various methods of stormwater treatment. At this facility, runoff from the Benton County Development Department property is captured and pumped into a bioswale. This bioswale is comprised of layers of rock, gravel, sand, and soil, and is...
Finding renewable sources of agricultural fertilizer will be necessary to ensure a stable food supply for future generations. Phosphorus is of particular concern, since mining phosphate rock is the main source and reserves are forecasted to deplete in the next 50 – 200 years. Human urine contains substantial amounts of...
Metal-Organic Frameworks (MOFs) are crystalline compounds formed from reacting a metal ion with an organic ligand. They represent a promising new avenue in materials science for gas separations and storage. Certain MOFs, in particular Mg-MOF-74, have shown a strong affinity for the capture of CO2. This project investigated a known...
Platinum and palladium surfaces are utilized as catalytic surfaces in the chemical industry. Understanding how hydrogen atoms interact with the metal surfaces will allow for further advancement in this area. Specifically, the interaction of hydrogen on the surface and subsurface of these metals was investigated using density functional theory calculations...
Real transportation fuels contain a wide range of hydrocarbon species, and this complexity poses challenges for modeling. Surrogates with a simpler blend of hydrocarbon reference fuels can approximate the physical and chemical characteristics of real fuels and enable practical simulation of the reacting flows that occur in engines and combustors....
Platelets undergo morphological changes essential to hemostasis upon activation at sites of vascular injury. The Rho GTPases Rac1, Cdc42, and RhoA drive these changes. Rho guanine nucleotide dissociation inhibitors (RhoGDIs) bind to the Rho GTPases to block the GDP from dissociating from the Rho GTPases, as well as anchoring the...
As nanoparticle (NP) research and development expands, the significance of NP biodistribution effects on toxicity increases. A reliable method for measuring NP biodistribution is critical. Hyperspectral Imaging (HSI) is capable of accurately quantitating NP biodistribution within embryonic zebrafish with incredibly high precision. Before HSI processing, the embryo must be sectioned...
The widespread use of engineered nanoparticles (ENPs) in industrial applications and consumer products makes their release to the environment inevitable. Understanding the aggregation behavior of ENPs is crucial to understanding their fate, transport and toxicology in aquatic systems. This study investigated the comparability of experimentally-determined and model-estimated attachment efficiencies for...
The measurement of extensional viscosity is important in many chemical, biomedical, agricultural, and engineering applications. The determination of extensional viscosity is generally difficult, expensive, and inaccessible outside of research labs. The development of a smartphone application (app) that could use a phone’s high-speed camera to measure this parameter could open...
The Micralyne microfluidic toolkit (μTK) was an instrument built by Micralyne in the early 2000’s. It was built for electrophoresis and has a sensitive laser-induced fluorescence detection system. The updates to the system were upgrading the control GUI from running in LabVIEW 5 (Windows XP, 2000) to LabVIEW 2012 (Windows...
Fluorescence spectroscopy is a powerful analytical technique due to bright signals that provide excellent measurement sensitivity. Many colors of fluorescent dyes are available to match the detection ranges of different equipments. Dyes can be chemically modified to bind to many different target analytes with high specificity1. Alternatively, sensors can be...
In order to support first-year women in engineering, a program was designed to help their transition to college and promote connection with other women. The program focused on three main areas based in research: mentor matching with mentee input, regular formal meetings in small mentoring groups, and the formation of...
Effective storage and release of low-to-moderate temperature thermal energy (e.g. solar thermal or geothermal) could be transformational for applications such as space heating/cooling, domestic hot water, or off-grid cooking. Good candidates for thermal energy storage in this temperature range include latent heat storage (LHS) systems and thermochemical energy storage (TCES)...
Coming of Age is a collection of ekphrastic poetry inspired by photographs taken throughout Oregon between 2012-2018. The collection traces the author's experience as she transitions from teenager to adult, struggles with change and loss, and studies to become a chemical engineer.
Key Words: ekphrastic poetry, prose poetry, poetry, photography,...
Nanoparticles (NPs) are generally defined as particles <100 nanometers (nm) in size in one dimension. Despite increasing industrial usage of TiO2 NPs in sunscreens, cosmetics, and water remediation little is known of their environmental behavior. The primary goal of this research was to develop a rapid method for determining the...
The purpose of this project was to optimize the biomass growth of Schizochytrium limacinum SR21. This was achieved by studying the effect of various concentrations of glucose, use of pure glycerol and purified crude glycerol as alternative carbon sources, and inhibition of cell growth with the presence of copper. The...
This study investigated learning in three engineering student clubs at a large public university. This included a small-sized chemical reaction car competition, a large-sized formula racing team, and an international humanitarian engineering club. Research methods included observations of work sessions (N=27) and semi-structured interviews (N=19). Using Cultural Historical Activity Theory...
Increased dependence on fossil fuels and concerns of anthropogenic climate change have led to increased interest in alternative energy sources. Liquid fuels derived from renewable raw materials have gained attention in recent years due to their similarity to petroleum-based fuels. Biofuels derived through hydrodeoxygenation have been found to be one...
The advancement of the US energy grid is a necessary task to undertake as renewable energies like wind and solar power become more and more prevalent in our energy sector. However, due to uncontrollable factors such as wind speed and cloud cover, the intermittence of these energy sources continues to...
This work introduces the design and fabrication of a green-sourced and mostly biodegradable microbial fuel cell for use in soft robotic applications from environmental sensing to wastewater remediation. Theorized from other biodegradable fuel cells, this prototype achieved maximum power densities of 4.0 x 10−4 W/m2 in the single-chambered design and...
Global energy needs are continuously increasing while fossil fuels remain an uncertain resource. With a growing population and demand for energy, alternative energy sources are being pursued to power the future. Fossil fuels are an unsustainable resource that brings along problems of climate change and atmospheric pollution. Concentrated solar power...
Copper antimony sulfide (CAS) is a ternary material that is of research interest for thin film photovoltaic applications due to its high absorption coefficient and tunable bandgap. The material is also ideal for sustainable manufacturing due the constituent elements being earth-abundant and less toxic than solar cell absorbers like gallium...
Monitoring phenylalanine (Phe) levels in the blood of individuals with phenylketonuria (PKU) is a critical component of therapy. Existing tests for PKU require high-resource laboratories, which are not available to many populations and cannot provide the real-time feedback required for effective therapy monitoring. It would be ideal to develop an...
Safety culture is a vital part of any organization. It describes how employees, on all levels, perceive safety at the particular organization. Measuring safety culture is fundamental to determining the environment of the organization. Using different measurement methods, including surveys, changes can be made to increase safety and improve safety...
The purpose of this project was to optimize the biomass growth of Schizochytrium limacinum SR21. This was achieved by studying the effect of various concentrations of glucose, use of pure glycerol and purified crude glycerol as alternative carbon sources, and inhibition of cell growth with the presence of copper. The...
As conventional energy sources begin to deplete, the need for alternative, renewable
energy becomes more necessary. Dimethyl ether (DME) fuel cells are a promising
energy source that could fulfill these demands. Compared to well-known fuel cell
fuels, such as methanol, DME has a low toxicity and high energy density.
Experimental...
Swelling soils cause millions of dollars of damage to buildings every year in the Unites States alone. One essential piece to understanding these soils is to understand how water moves through them. Hydraulic conductivity is a measure of how easily water flows through a soil. Currently, the most common method...
T. pseudonana biosilica and live cells was explored as a biosensor for detection of the explosive compound 2,4,6-trinitrotoluene (TNT) in aqueous solution. The diatom frustule is an intricately nanostructured, highly porous biogenic silica material derived from the shells of microscopic algae called diatoms. This material emits strong visible blue photoluminescence...
Stormwater picks up pollutants as it flows over impervious surfaces before ending up in water resources. Best management practices are implemented to remove pollutants from stormwater. Puralytics manufactures a stormwater treatment product called the LilyPad. The LilyPad consists of a titanium dioxide nanoparticle photocatalyst immobilized on polypropylene substrate. Treatment of...
Incompatibility between Fenton’s Reagents and a potassium dichromate COD test provides interference that prevent accurate measurements of the concentration of organics from oxidized samples. Several treatment options were tested to remove this interference. Oxidation of reagents was eliminated as a potential method for removal of interference due to sample contamination....
Zero valent iron nanoparticles effectively remediate groundwater contaminants due to their catalytic properties and enhanced surface area. However, these properties contribute to particle agglomeration, decreasing their effectiveness. In this study, we examined the effect of two stabilizing agents (gum arabic (GA) and sodium carboxymethyl cellulose (CMC)) on particle stability, toxicity,...
Insoluble surfactants are unique molecules that have the ability to manipulate interfacial properties, becoming useful in numerous applications such as detergents, wetting agents, emulsifiers, foaming agents, dispersants, and more. Interfacial rheology is a field that attempts to characterize the flow properties of insoluble surfactants by exerting a stress on the...
This project discuses the design of a novel apparatus for measuring the interfacial rheological properties of a complex interface while measuring the concentration of redox species within the sub-phase. Preliminary measurements made using the apparatus are also presented. The objective of the preliminary experimentation was to simultaneously measure the interfacial...
Assembly and genotyping of polyploid genomes poses many problems due to the complex nature of polyploid data, including the inability to determine allelic dosage and mixed inheritance patterns. This study was the first application of POLiMAPS genotyping on whole genome sequences without using cross information. In this study, whole genome...
The art of medicine refers to physicians’ abilities to skillfully navigate interpersonal interactions with patients. These interactions are vital to the formation of exceptional physician-patient relationships. Certain elements of healthcare today such as the advancement of diagnostic tests, the emergence of the electronic medical record, and the presence of market...
This project explores the relationship between microsecond-timescale dynamic surface tension (DST) and measurable thermal inkjet printing parameters. Dynamic surface tension affects many aspects of printing, including printing speed and ink drop shape. In addition to this, DST is a physical input parameter for HP’s in-house computational fluid dynamics program. HP...
Polystyrene thin film surfaces are commonly used to study the interactions of macromolecules, such as proteins, with surfaces. Polystyrene films oxidized in UV light become more hydrophilic, however these surfaces have a limited shelf life because they are reduced over time. Experiments were performed to determine the effect of radiation...
Human use of fossil fuels has caused a dramatic shift in the earth’s environment, with global temperatures rising and ecosystem health declining. The need for the human species to reduce our reliance on fossil fuels is apparent. This will be achieved by replacing conventional energy resources with sustainable alternatives, and...
Every year in the late summer, patches of the Columbia River estuary begin to turn red. These patches are blooms of mixotrophic ciliates (Myrionecta rubra or Mesodinium rubrum/major) (MR) that ingest the chloroplast of their prey, the cryptophytes (CR) Teleaulax amphioxeia (Peterson et al., 2013), and use the acquired organs...
Metal-organic frameworks (MOFs) are crystalline porous material distinguished for high free empty volume and pore tunability. MOF-74(Ni) was previously shown to be effective in adsorbing carbon dioxide, methane, and hydrogen. Microwave-assisted synthesis of MOF-74(Ni) was shown to lower reaction time from days to hours. In this thesis, experimental conditions of...
This paper presents a brief history of social dance at Oregon State University (OSU) and discusses its key elements and context. Social dance has been part of campus life at OSU since the university was founded. Initially, dance was a social activity and means to interact with others, but as...
Anti-reflective coatings are applied to substrates to increase the transmittance of light in the visible range of wavelength 400 – 800 nm through the substrate by changing the refractive index at the surface and directing more light through the substrate rather than being reflected away. This project investigated the possibility...
Water-soluble quantum dots obtained through ligand exchange are widely applicable for biological imaging and marking, LEDs, and photovoltaics. Lipoic acid (LA) was reduced to dihydrolipoic acid (DHLA) using 365-nm soft UV light in a process known as photoligation, and ligand exchange with dodecanethiol-capped CuInS₂-ZnS core-shell quantum dots occurred. The reaction...
Tomato flowers (Solanum lycopersicum) were used as a model system to investigate flower color modification by alteration of the carotenoid biosynthetic pathway, due to their ease of transformation and short time from seed to flowering. Tomato flowers are naturally bright yellow, primarily due to the accumulation of violaxanthin. Violaxanthin is...
The inhibitory effects of Corexit 9500A, Alaska North Slope Crude oil (ANSC), and mixtures of the two on the ammonia-oxidizing bacteria, Nitrosomonas europaea, and the ammonia-oxidizing archaea, Nitrosopumilus maritimus, were investigated. Corexit 9500A was found to be minimally toxic to both microorganisms with concentrations of 2000 and 3000 ppm yielding...
Freeze-drying, or lyophilization, has shown great promise in addressing many of the logistical challenges of storing and preserving red blood cells (RBCs). A crucial part of any future RBC lyophilization protocol is the primary drying temperature, which affects the sample drying rate and the dried cake’s ability to form a...
On April 20th, 2010 the Deepwater Horizon drilling rig in the Gulf of Mexico malfunctioned leading to a 4.9 million barrel oil spill. The released oil affected marine life, coastal ecosystems, and the economic framework of the Gulf of Mexico. The Gulf spill spurred research on absorbent materials and engineering...
Innovative nanoelectromechanical switches (NEMS) have the prospects to reduce device actuation voltages as compared to traditional semiconductor devices. Current research on NEMS seeks to avoid irreversible adhesion at the nanoscopic level, which results in device failure. Minimizing leakage currents and increasing device longevity are additional goals of this approach. The...
Climate change, population growth, aging infrastructure, poor water management, and aquifer depletion are reducing US water supply. Increasing water scarcity will lead to an inability to support agriculture, industry, energy, and municipal demand that will negatively affect US economic growth and national security. Traditional water policy measures of expanding supply...
The Interactive Virtual Laboratories (IVLs) are a series of two-dimensional simulations designed to help students conceptually learn difficult concepts in thermodynamics. Three studies were performed to help elucidate how the IVLs affect student learning. In the first study, eight students were observed while completing one of the IVLs. The students...
The need for clean energy continues to rise as the earth’s non-renewable resources continue to be depleted to satisfy energy demands. One plausible renewable energy source exists in biomass-powered fuel cells.¹ While there are several ways to convert sugars to energy, one interesting approach is to convert the sugars to...
Pb(Zr₁₋ₓTiₓ)O₃ (PZT) is a common piezoelectric and ferroelectric thin film material with a wide variety of applications, including ferroelectric random access memories, novel thin film transistors, and microelectromechanical systems (MEMS). The most common substrate for PZT in all of these areas has been platinum-coated silicon. Alternative substrates are desired for...
Titanium dioxide, in the anatase form, is a photocatalyst and has applications in water pollution reduction. Efficiency can be improved with a graphene substrate, which delays electron-hole recombination and may reduce the band gap. In this work, we determine if graphene can also act as a morphactant, changing the shape...
Amphiphilic gold nanoparticle surfactants can self-assemble at oil-water interfaces to form stable Pickering emulsions. These nanoparticle surfactants have previously been synthesized by functionalizing gold nanoparticles with thiol terminated polyethylene glycol (PEG-thiol), and subsequently with an alkane-thiol. It is necessary to improve the bio-compatibility of the nanoparticles if they are to...
Tetrachlorethene (PCE) and trichloroethene (TCE) were common solvents used in the 1970’s that are now frequently observed groundwater contaminants. One method of remediating these contaminants is in-situ bioremediation that uses a dechlorinating microbial population. The microbial population performs the sequential reductive dechlorination of PCE and TCE to cis-1,2-dichloroethene (c-DCE), vinyl...
The inhibitory effects of (Ag⁺) and silver nanoparticles (Ag NP) 3-5 nm in diameter (stabilized with polyvinylpyrrolidone (PVP)) and 20 nm (stabilized with citrate) on nitrification rates of the model ammonia-oxidizing bacteria (AOB) Nitrosomonas europaea were investigated. Experimental solutions contained HEPES buffer and ammonia (NH₃) in the presence and absence...
The memristor is a resistive switching random access memory (RRAM) with a basic metal/insulator/metal (MIM) structure. These nano devices are nonvolatile, have a conceptually simple crossbar device structure, are power efficient and have the capability of switching between high and low resistance states in nanoseconds making them promising to replace...
A system to reversibly extract Pb²⁺ ions from aqueous solutions using spiropyran functionalized nanofibers was proposed. Spiropyrans are photochromic compounds which undergo a conformational change that alters their physical properties and makes Pb²⁺ binding possible upon irradiation with UV light (365 nm). Irradiation with green light (525 nm) reverses this...
The purpose of this study is to investigate the use of recombinant lignin degrading enzyme, maganese peroxidise (rMnP), to detoxify inhibitors for theoptimization of ethanol production from lignocellulosic biomass. The negative effects of inhibitors: vanillin, furfural, hydroxymethylfurfural, and syringaldehyde on Saccharomyces cerevisiae and Pichia pastoris yeast cell growth in revealed...
Biosphere models predict the transport of radionuclides in the environment with an end goal of assessing the possible risk to humans. Little data exists to support these mathematical biosphere models. The objectives of this work were to verify foliar uptake in biosphere models using experimental data, compare existing biosphere models...
The cross over from batch nanoparticle synthesis to continuous synthesis processes is crucial to the commercialization of these materials. This project reports comparative studies of batch and continuous synthese of copper nanoparticles by the polyol method. Continuous synthesis of copper nanoparticles was done utilizing a stainless steel micro-mixer that yielded...
A system of Photoactuated Droplet Microfluidics (PDM), in which a droplet of
fluid is moved by way of the manipulation of the wettability of a spiropyran
functionalized surface via irradiation with ultraviolet and visible light, was proposed. The
photochromic behaviors of several species of spiropyran were studied and a procedure...