The motivation for undertaking this research was to increase the understanding of processing colloidal semiconductor nanocrystals and thin films metallic glasses to enable their wider application in future devices. This research covered two unique materials, lead selenide (PbSe) nanocrystals and thin film metallic glass alloy of zirconium copper aluminum nickel...
The corrosion and degradation of Ni and its alloys in supercritical carbon dioxide (Sc-CO2) is an emerging issue for material selection and implementation of Sc-CO2 thermal cycles in industry. In this study, we apply density functional theory (DFT) to study the initial steps of carburization of the Ni (111) surface...
The development of solution-based methods for deposition of different thin film material is presented as an alternative to high cost vacuum-based methods. For certain materials, vacuum techniques are unsuitable for processing. Additionally, vacuum-based processes present high capital costs associated with equipment, and slow processing times. Atmospheric pressure solution based techniques...
The interactions of chemical species with a solid surface play a role in many everyday applications such as heterogeneous catalysis, corrosion, and degradation reactions. Understanding the reaction kinetics and thermodynamics via rate constants and equilibrium constants, which require knowledge of the adsorbed species’ entropy, is essential for tuning these surface...
Utilization of solar energy or wind energy for electricity production is inherently challenging due to the diurnal and seasonal variations and normal intermittency. Effective, high efficiency storage methods need to be developed for further advancing renewable energy utilization. Endothermic chemical processing and thermochemical energy storage can be both employed as...
Nitrosomonas europaea carries out the first step in the biological nitrogen removal process in wastewater treatment by oxidizing ammonia to nitrite. It has been shown to be sensitive to a wide range of contaminants. The antibiotic oxytetracycline and the heavy metals chromium and silver have been found in wastewater influent....