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The interaction of CO, N₂, NO, and O₂ with fourth period metal dihalides

Creator:: Van Leirsburg, Dean Alan
Resource Type:: Dissertation
Full Text:: for the in Chemistry (Major) presented on Ph. D. (Degree) Title: THE INTERACTION OF CO, N2, NO

Development, validation and the application of a congener specific photodegradation model for PBDEs

Creator:: Zeng, Xia
Abstract:: The thermodynamic properties of 39 PBDEs have been calculated using Gaussian 03 on the B3LYP/6-31G(d)//B3LYP/6-31G(d) level. The PBDE congeners' enthalpies of formation increase with increasing number of bromines and show a strong dependence on the bromine substitution pattern. The effects of bromine substitution pattern have been quantitatively studied by GAM...
Resource Type:: Dissertation
Full Text:: photodegradation of PBDEs. Photodegradation experiments were conducted for octa-BDE technical mixture and its

Label-free mass spectrometry-driven methods for elucidating adaptive responses of the hepatic mitochondrial proteome in an alcoholic fatty liver disease model

Creator:: Tzeng, Shin-Cheng
Abstract:: Alcoholic liver disease (ALD) continues to be one of the major public health problems in the United States and worldwide. Complicated by factors including gender, polymorphisms of alcohol-metabolizing enzymes, immunologic factors, exposures to other substances/drugs, hepatic viral infections, nutritional deficiencies, and obesity, ALD is a complex disease that requires a...
Resource Type:: Dissertation
Full Text:: datasets with high technical precision were obtained. By taking advantage of the information-rich

Novel monolithic columns for microscale liquid chromatography and capillary electrochromatography

Creator:: Chirica, Gabriela S.
Abstract:: The challenges prompted by miniaturization of chromatographic systems have led scientists to explore new avenues in the synthesis of stationary phases. Packed capillary columns have found limited application in routine analysis due to a number of technical difficulties, most of which are attributable to the frits. New column designs insure...
Resource Type:: Dissertation
Full Text:: limited application in routine analysis due to a number of technical difficulties, most of which are

Precursor-directed Biosynthesis and Total Synthesis of Aniline-containing Natural Products from the Endophytic Fungus Chalara sp. 6661

Creator:: Khoshbakht, Mahsa
Abstract:: Chalaniline A, an unusual xanthone-like aminofulvene with modest cytotoxicity, and chalaniline B [1-anilino-2,8-dihydroxy-3-(hydroxymethyl)xanthone], an antibacterial aminoxanthone, were previously isolated by Loesgen and coworkers from vorinostat-treated Chalara sp. 6661. Of note, the anilino moiety found within both chalaniline structures originates from biotransformation of the HDAC inhibitor vorinostat (SAHA, suberanilohydroxamic acid) by...
Resource Type:: Dissertation
Full Text:: and coworkers from vorinostat-treated Chalara sp. 6661. Of note, the anilino moiety found within

Organic Crystalline Solids : Investigating their Capability, Storage Mechanism and Structural Evolution in Dual-Ion Batteries

Creator:: Rodríguez Pérez, Ismael A.
Abstract:: Widespread installation of renewable energy sources, such as wind and solar, has been delayed by the lack of suitable stationary energy storage solutions. Current large-scale technologies, such as pumped hydro and compressed air, are geographically restricted. This is where electrochemical energy storage - batteries or hybrid capacitors can play a...
Resource Type:: Dissertation
Full Text:: revealed that optimization in DIBs is crucial, where several technical issues have prevented the

Application of laser spectroscopy to structure and dynamics of small molecular systems

Creator:: Bozlee, Brian J.
Abstract:: A variety of laser spectroscopic methods are employed in this thesis research for studies of CF₃NO, an interesting model photodissociative system, and for investigation of low energy rotations and vibrations of small molecules and low molecular weight clusters in free jet expansions. Nonradiative energy decay for electronically excited CF₃NO is...
Resource Type:: Dissertation
Full Text:: transient separation of CF3 and NO photofragments in the matrix cage or appreciable decay through a low

The atmospheric chemistry of particulate-bound polycyclic aromatic hydrocarbons : concentration, prediction, laboratory studies, and mutagenicity

Creator:: Jariyasopit, Narumol
Abstract:: The trans-Pacific atmospheric transport of particulate matter (PM)-bound polycyclic aromatic hydrocarbons (PAHs) to remote sites in western North America has been well documented and has triggered research questions regarding to atmospheric transformation of PM-bound PAHs and the potential impacts on human health from their inhalation exposure. In this dissertation, field...
Resource Type:: Dissertation
Full Text:: the NO concentrations, indicating that the NPAH and OPAH were primarily associated with local

Application of the least squares criterion to the determination of molecular compliance constants

Creator:: Ottinger, Robert Stanley
Abstract:: The development of a least squares model for the determination of compliance constants from various combinations of vibration frequency, mean square amplitudes of vibration and centrifugal distortion data is discussed. The resultant model is applied to frequency and mean square amplitude data for NO₂ and N₂O₄ and to frequency and...
Resource Type:: Dissertation
Full Text:: compliance constant treatment of the same problem. It can be assumed with no loss of generality that

Gas chromatography of metal halides

Creator:: Dennison, James Eugene
Abstract:: An all-glass gas chromatograph was developed for the analysis of corrosive metal halides. Included in the apparatus is a new liquid sampling system designed for fast repetitive sampling of corrosive liquids in an inert atmosphere. A flame photometer detector was developed to permit the detection of corrosive solutes in the...
Resource Type:: Dissertation
Full Text:: metal chlorides, including GeC14, SnC14, AsC13 and TiC14 gave almost symmetrical peaks. No evidence

ScholarsArchive@OSU

The interaction of CO, N₂, NO, and O₂ with fourth period metal dihalides

Development, validation and the application of a congener specific photodegradation model for PBDEs

Label-free mass spectrometry-driven methods for elucidating adaptive responses of the hepatic mitochondrial proteome in an alcoholic fatty liver disease model

Novel monolithic columns for microscale liquid chromatography and capillary electrochromatography

Precursor-directed Biosynthesis and Total Synthesis of Aniline-containing Natural Products from the Endophytic Fungus Chalara sp. 6661

Organic Crystalline Solids : Investigating their Capability, Storage Mechanism and Structural Evolution in Dual-Ion Batteries

Application of laser spectroscopy to structure and dynamics of small molecular systems

The atmospheric chemistry of particulate-bound polycyclic aromatic hydrocarbons : concentration, prediction, laboratory studies, and mutagenicity

Application of the least squares criterion to the determination of molecular compliance constants

Gas chromatography of metal halides

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