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Radiosulfur exchange studies in the liquid sulfur dioxide--thionyl fluoride system

Creator:: DeGroot, Peter Bernard
Resource Type:: Dissertation
Full Text:: --thionyl fluoride system AN ABSTRACT OF THE THESIS OF PETER BERNARD DEGROOT for the DOCTOR OF PHILOSOPI

Hydrogen abstraction from substituted t-butylbenzenes

Creator:: Harvey, Robert Louis
Abstract:: A study of the relative rates of the alkyl hydrogen abstraction from a series of meta and para substituted t-butylbenzenes by the chlorine atom at 70°C has been carried out. Application of the Hammett equation yielded a ρ value of -0.44 for the para compounds. Possible explanations for the non-linearity...
Resource Type:: Masters Thesis
Full Text:: Hydrogen abstraction from substituted t-butylbenzenes AN

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

Creator:: Raghavan, Ramaswamy Srinivasa, 1941-
Resource Type:: Dissertation
Full Text:: SYSTEM Abstract approved Redacted for Privacy Dr. Peter K. Freeman An investigation of some potential

Reactive intermediates in the tetracyclo-[3.3.0.0² ⁷.0⁴ ⁶] octane, the tetracyclo-[3.3.0.0² ⁴.0³ ⁷] octane, and related ring systems containing the norbornane skeleton

Creator:: Ziebarth, Timothy Dean
Resource Type:: Dissertation
Full Text:: Privacy pp Dr. Peter K. Freeman The base induced thermal decompositions of tricyclo- [3.2.1.03'6]octan

Carbonium ion intermediates in the tetracyclo [4,3.0.0²[superscript ,]⁴.0³[superscript ,]⁷] and tetracyclo [4.3.0.0²[superscript ,]⁴.0³[superscript ,]⁸] - nonane ring systems

Creator:: Stevenson, Brian Keith
Resource Type:: Dissertation
Full Text:: ' 4. 03' 8]- NONANE RING SYSTEMS Redacted for Privacy Abstract approved: . Peter K. Freeman The

The photochemistry of some polyhalobenzenes

Creator:: Huang, Yo-hsin
Resource Type:: Masters Thesis
Full Text:: Dr. Peter K. Freeman The photodechlorination of fluoropentachlorobenzene was carried out by

A study of the chemistry of diisopropyl-, cyclopropylisopropyl-, and dicyclopropylcarbene

Creator:: Wuerch, Stephen E.
Abstract:: The effect of the conjugation with cyclopropyl rings on the activation parameters for the formation of carbenes from the corresponding diazo compounds was investigated using diisopropylcarbene (46), cyclopropyl-isopropylcarbene (47), and dicyclopropylcarbene (48). Each of these three carbenes was generated by the thermolysis of the parent benzenesulfonylhydrazone potassium salts using DMSO...
Resource Type:: Masters Thesis
Full Text:: . Peter K. Freeman The effect of the conjugation with cyclopropyl rings on the activation parameters for

The photodebromination of polybromobenzenes

Creator:: Couch, Tara Lin
Resource Type:: Dissertation
Full Text:: Polybromobenzenes. Abstract approved: Peter K. Freeman The photodebromination of a series of polybromobenzenes

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Creator:: Balyeat, John Robert
Abstract:: The tosylhydrazones of exo-3-deuteriocamphor and 2- deuterio-2,4-dimethy1-3-pentanone were treated with Nbromosuccinimide (NBS) and pyruvic acid to regenerate the parent ketones. The ketones from the pyruvic acid cleavage show a significant loss of deuterium. The ketones from the NBS cleavage show no loss of deuterium, indicating that stereochemical integrity at. C[subscript...
Resource Type:: Masters Thesis
Full Text:: -DIMETHYLNORBORNANE Redacted for Privacy Abstract approved: Dr. Peter K. Freeman The tosylhydrazones of exo-3

Photochemistry of some bromoarenes

Creator:: Jang, Jung-suk
Abstract:: The photodebromination of selected bromoarenes has been studied at 300 nm to determine the the possible mechanistic pathways leading to product. Irradiation of 4-bromobiphenyl (BpBr) at this wavelength leads to the product biphenyl. The quantum yield of intersystem crossing (0.98) and quenching studies with cis-1 ,3-pentadiene suggest that the reaction...
Resource Type:: Dissertation
Full Text:: : Photochemistry of Some Bromoarenes Abstract approved: Redacted for Privacy Peter K. Freeman The

ScholarsArchive@OSU

Radiosulfur exchange studies in the liquid sulfur dioxide--thionyl fluoride system

Hydrogen abstraction from substituted t-butylbenzenes

Reactive intermediates in the tricyclo- [3.2.1.0²,⁴] octane ring system

Reactive intermediates in the tetracyclo-[3.3.0.0² ⁷.0⁴ ⁶] octane, the tetracyclo-[3.3.0.0² ⁴.0³ ⁷] octane, and related ring systems containing the norbornane skeleton

Carbonium ion intermediates in the tetracyclo [4,3.0.0²[superscript ,]⁴.0³[superscript ,]⁷] and tetracyclo [4.3.0.0²[superscript ,]⁴.0³[superscript ,]⁸] - nonane ring systems

The photochemistry of some polyhalobenzenes

A study of the chemistry of diisopropyl-, cyclopropylisopropyl-, and dicyclopropylcarbene

The photodebromination of polybromobenzenes

Carbene chemistry : I. Stereochemical integrity at Cα in ketone tosylhydrazones : II. Hydrogen migration in 2-carbena-6, 6-dimethylnorbornane

Photochemistry of some bromoarenes

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