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Filtering by: Alternative title ssim Report no. 83-9 Degree Field Chemistry Resource Type Article

High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Creator:

Erickson, Blake Alexander, Ju, X., Nibler, Joesph W., Beaudry, C. M., and Blake, T. A.

Abstract:

Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...

Resource Type:

Article

Full Text:

= 0.1120700(9), DJ = 1.51(3) x10 -8 , DJK = 3.42(15) x10 -8 . We note that the B0 value is significantly