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Kinetics of the decomposition of organic reactor coolants

Creator:: De Halas, Don Richard
Resource Type:: Dissertation
Full Text:: KINETIC' OF THE DECOMPOSITION OF ORGANIC REACTOR COOLANTS DON RICHARD DE HALAS A THESIS submitted to

A synthesis of 6-n-propyl-7-methyltetralin-5-C¹⁴

Creator:: Odell, Norman Raymond
Resource Type:: Dissertation
Full Text:: . SYNTHESIS OF 146-n- PROPYL-7-.M.ETBYLTETRALIN- 5- C by NORMAN RAYMOND ODELL A THESIS submitted 'Lo

Syntheses of large ring hormone analogs

Creator:: Yue, Stephen T.
Abstract:: The (±) 8,9:13,14-diseco-norestradiol, a large ring hormone analog, and its related derivatives, were prepared by a ring expansion approach. The key step of this approach is the establishment of the benzocyclododecenone system via the Caubere reaction. This step not only provides a favorable ring size, it also sets the necessary...
Resource Type:: Dissertation
Full Text:: : SYNTHESES OF LARGE RING HORMONE ANALOGS Abstract approved: _Redacted for privacy Richard W. Thies The

Exploratory studies directed toward the synthesis of large ring hormone analogs

Creator:: Chiarello, Ronald Harry
Resource Type:: Dissertation
Full Text:: TOWARD THE SYNTHESIS OF LARGE RING HORMONE ANALOGS Abstract approved: Redacted for privacy Richard W

Substituent control in the oxy-Cope rearrangements of 1-vinyl-trans-cyclotridec-3-en-1-ol systems

Creator:: Daruwala, Khushroo Peshotan
Abstract:: The thermal and anionic rearrangements of substituted 1-vinyltrans- cyclotridec-3-en-l-ol compounds have been studied to determine what effects substituents would have on the sigmatropic shift when placed on the two positions of the 1-vinyl group. For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols gave both the [3,3] and [1,3] shift products of...
Resource Type:: Dissertation
Full Text:: : Redacted for privacy (Richard W. Thies) The thermal and anionic rearrangements of substituted 1-vinyl

Thermal [pi]-route rearrangement of 4-cycloheptane-1-methyl acetate

Creator:: Schick, Lawrence Edward
Abstract:: Pyrolysis of 4-cycloheptene-l-methyl acetate under flow conditions at 285° gives only rearranged bicyclic acetates and hydrocarbons rather than the anticipated simple elimination product methylenecyclohept- 4-ene. These rearranged acetates have the same structures and are formed in virtually the same relative percentages as those observed in the "π- route" solvolysis of...
Resource Type:: Dissertation
Full Text:: - Cycloheptene- 1- methyl Acetate Redacted for Privacy Abstract approved: Richard W. Thies Pyrolysis of 4

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

Creator:: Billigmeier, James Earl
Resource Type:: Dissertation
Full Text:: Redacted for privacy Dr. Richard W. Thies The thermal rearrangements of trans-l-vinylcyclodec-3-en-l-ol

Ring expansion reactions of alkoxides and their application toward synthesis of large ring hormone models

Creator:: Seitz, Earl Philip
Abstract:: The potassium salts of a series of 1-vinylcycloalk-3-en-l-ols were found to undergo ring expanding [1, 3]-sigmatropic shifts at 25° when dissolved in hexamethylphosphoramide (HMPA) or 1, 2-dimethoxyethane (DME) with 18-crown-6. The yields and reaction rates were compared with those of the corresponding Siloxy-Cope ring expansions. These anionic cases showed about...
Resource Type:: Dissertation
Full Text:: Redacted for privacyAbstract approved: Richard W. Thies The potassium salts of a series of 1-vinylcycloalk

Synthesis of large-ring analogs of estrone

Creator:: Pierce, John Robert
Resource Type:: Dissertation
Full Text:: privacy Richard W. Thies Various ring expansion routes from benzo medium-ring ketones to large-ring

Part I: Synthetic Studies toward C10-functionalized Lycopodium Alkaloids. Part II: Exploration of the Pummerer Cyclization and Its Application to the Total Syntheses of the Abietane Diterpenoids

Creator:: Li, Xin
Abstract:: This dissertation is separated into two parts according to the two major distinct research projects. In Part I, the full account of synthetic studies toward C10-functionalized lycopodium alkaloids is described. In Part II, the detailed discussion on the exploration of the Pummerer cyclization methodology and its application to the total...
Resource Type:: Dissertation
Full Text:: of multiple abietane diterpenoids (ent-triptobenzene T, vitexifolin C, hinokiol, 4-epi

ScholarsArchive@OSU

Kinetics of the decomposition of organic reactor coolants

A synthesis of 6-n-propyl-7-methyltetralin-5-C¹⁴

Syntheses of large ring hormone analogs

Exploratory studies directed toward the synthesis of large ring hormone analogs

Substituent control in the oxy-Cope rearrangements of 1-vinyl-trans-cyclotridec-3-en-1-ol systems

Thermal [pi]-route rearrangement of 4-cycloheptane-1-methyl acetate

Siloxy-cope and oxy-cope rearrangements of the cis- and trans-1-vinylcyclodec-3-en-1-ol systems ; Acid-catalyzed rearrangement of cis-bicyclo [6.1.0] nonane-cis- and trans-9-methanols ; An effective two-carbon ring-expansion

Ring expansion reactions of alkoxides and their application toward synthesis of large ring hormone models

Synthesis of large-ring analogs of estrone

Part I: Synthetic Studies toward C10-functionalized Lycopodium Alkaloids. Part II: Exploration of the Pummerer Cyclization and Its Application to the Total Syntheses of the Abietane Diterpenoids

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