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Filtering by: Creator Davis, Eva Ann Degree Field Chemistry Subject Chemical reactions

Kinetics and mechanisms of nucleophilic displacement reactions with S-methyl-S-phenyl-sulfiminium perchlorate

Creator:

KiYokane, Richard Junji

Resource Type:

Masters Thesis

Full Text:

studied by Bunton, Tillett, and co-workers (10, 11-16) and by Davis (10, 17). The rate law is first
The kinetics and mechanisms of the cleavage of some sulfur-sulfur bonds

Creator:

Favstritsky, Nicolai Alexander

Resource Type:

Dissertation
Intramolecular transfer of complexed radicals as a possible explanation for long-range substituent effects observed in hydrogen abstraction reactions

Creator:

Newkirk, David Dudley

Abstract:

The relative rates of hydrogen abstraction from 1-phenylalkanes and a,w-diphenylalkanes using N-bromosuccinimide and bromotrichloromethane were determined at 70°C. In both cases the reactions were photoinitiated. Only benzylic bromination was observed. The 1-phenylalkanes reacted with both reagents to give rates largely independent of substrate. Similarly, the rate of the reaction between...

Resource Type:

Dissertation

Full Text:

is due my parents and Miss Mary Ann McKown for their encouragement and prayers during this work