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Filtering by: Creator Munson, Mary K. Remove constraint Creator: Munson, Mary K. Degree Field Chemistry Remove constraint Degree Field: Chemistry Subject Organic compounds -- Synthesis Remove constraint Subject: Organic compounds -- Synthesis

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Cyclization of organolithium and -zirconium compounds ; Rearrangements of selected anionic compounds in highly disassociative solvents

Creator:

Bass, Lawrence W.

Abstract:

Intramolecular cyclization of organometallic compounds represents a promising tool for synthesis. The reaction involves exothermic consumption of intramolecular double bonds via insertion into a carbon metal sigma bond. This represents an intramolecular example of the reaction type responsible for metal catalyzed polymerization of olefins. Organolithium reagents were found to cyclize...

Resource Type:

Dissertation

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6-Exo-Dig (favored) ZY k 3-Endo-Dig (favored) 5 The mode of ring closure is designated by the
The synthesis of nonactic acid

Creator:

Arco, Manuel Jose

Abstract:

Alkylation of propylene oxide with 2-lithiofuran gave alcohol I, which was smoothly converted to acetylfuran II. hydrogenation of II over rhodium on charcoal followed by Jones' oxidation afforded ketone III. Further transformation into IV was accomplished via a Wittig reaction followed by saponification with methanolic sodium hydroxide. Hydroboration of the...

Resource Type:

Dissertation

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presented August 15, 1975 Typed by Mary Jo Stratton for Manuel Jose Arco ACKNOWLEDGEMENTS I feel
Total synthesis of (+)-bourgeanic acid and conformational analysis of its dilactone

Creator:

Johnson, Alan T. (Alan Thomas), 1957-

Resource Type:

Dissertation

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must also thank my parents, Carl and Mary, for their support and for giving me the opportunity to
The synthesis and chemistry of strained bicyclic systems

Creator:

Scerbo, Louis

Abstract:

A facile route to bicyclo(2.1.1)hexanes was developed involving the intramolecular photocyclization of 1, 5-hexadien-3-one to bicyclo(2.1.1)hexan-2-one. A study of the chemistry of bicyclo-(2.1.1)hexan-2-one was undertaken. Deuterium exchange and borohydride reduction demonstrated the strain present in the ketone. Further evidence was obtained from the failure to introduce substituents alpha to the...

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Dissertation

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bicyclo(2. 1. 1)hexane derivatives 6 through 11 (115, 116, 117). 6 Cl CO2H 7 cl 10 OH L;k

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Academic Affiliation

Chemistry4

Advisor

White, James D.2
Bond, F. Thomas1
Gleicher, Gerald Jay1

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Current results range from 1968 to 1991

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Creator

Arco, Manuel Jose1
Bass, Lawrence W.1
Johnson, Alan T. (Alan Thomas), 1957 1
Scerbo, Louis1

Date

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Current results range from 1968 to 1990

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Decade

1990-19991
1970-19792
1960-19691

Degree Field

Chemistry[remove]4

Degree Level

Doctoral4

Degree Name

Doctor of Philosophy (Ph.D.)4

Language

English [eng]4

Non-Academic Affiliation

Oregon State University. Graduate School4

Peer Reviewed

No4

Resource Type

Dissertation4

Rights Statement

Copyright Not Evaluated4

Subject

Organic compounds -- Synthesis[remove]4
Lichens1
Stereochemistry1

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