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Creator:: Bolesta, Richard Edward
Abstract:: The thermolysis of trans-1 -trimethylsiloxy- 1-vinylcyclotridec- 3-ene (VI-OTMS) led to the formation of two major products: 4-vinylcyclotridecanone (VII) and cyclopentadec-5-en-l-one (VIII) after hydrolysis. Ketone VII is produced by a concerted [3, 3] sigmatropic shift, while ketone VIII is formed by a [1, 3] sigmatropic shift with a concerted or diradical...
Resource Type:: Masters Thesis
Full Text:: -ol System by Richard Edward Bolesta A THESIS submitted to Oregon State University in partial

Creator:: Daruwala, Khushroo Peshotan
Abstract:: The thermal and anionic rearrangements of substituted 1-vinyltrans- cyclotridec-3-en-l-ol compounds have been studied to determine what effects substituents would have on the sigmatropic shift when placed on the two positions of the 1-vinyl group. For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols gave both the [3,3] and [1,3] shift products of...
Resource Type:: Dissertation
Full Text:: : Redacted for privacy (Richard W. Thies) The thermal and anionic rearrangements of substituted 1-vinyl

Creator:: Boop, Janice Lee
Abstract:: The reaction of cyclodeca-1,215triene with mercuric salts gave only rearranged hydrocarbon, tricyclo[4.4.0.0²'⁴]deca-5ene in acetic acid. Other catalysts [Rh(CO)₂C1]₂ and AgC10₄ gave the same rearranged hydrocarbon. The isomerization is proposed to proceed through a "metalcomplexed" carbenoid intermediate. The reaction of bicyclo[7.1.0 ]deca-213diene gave oxymercurated products.
Resource Type:: Masters Thesis
Full Text:: for Privacy Dr. Richard W. Thies The reaction of cyclodeca-1,215triene with mercuric salts gave

Creator:: Schick, Lawrence Edward
Abstract:: Pyrolysis of 4-cycloheptene-l-methyl acetate under flow conditions at 285° gives only rearranged bicyclic acetates and hydrocarbons rather than the anticipated simple elimination product methylenecyclohept- 4-ene. These rearranged acetates have the same structures and are formed in virtually the same relative percentages as those observed in the "π- route" solvolysis of...
Resource Type:: Dissertation
Full Text:: - Cycloheptene- 1- methyl Acetate Redacted for Privacy Abstract approved: Richard W. Thies Pyrolysis of 4

Creator:: Banks, Richard Charles
Abstract:: PART I. A chemical examination of the materials toxic to fish in kraft pulp mill wastes has been made as part of a water pollution study. Thirty gallons of "foul condensate" from a typical kraft mill gave 14 g of organic material when extracted with methylene chloride, and an additional...
Resource Type:: Dissertation
Full Text:: Rearrange 13-lent of 1, 2-Diviny1-1, 2-Cyclohexanediol by Richard Charles Banks A THESIS submitted to

Creator:: Huff, Richard Royce
Resource Type:: Masters Thesis
Full Text:: UNDER ELECTROPHILIC SUBSTITUTION COlIDITIONS by RICHARD ROYCE HUFF A THESIS submitted to

Creator:: Schatz, Bruce Stewart
Resource Type:: Dissertation
Full Text:: . 45 X 10-4sec-1 at 152', k = 7. 02 X 10-4sec-1 at 165', Ea a 29. 4 kcal /mole and AS _ - 7 e. u. at

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