Normal adult rats absorbed and metabolized C¹⁴-labeled acetate
rapidly. The greatest percentage of the administered radioactivity
was recovered in the expired CO₂, however small amounts of radioactivity
were also found in the urine and feces. There were two rates
of C¹⁴O₂ elimination in normal adult rats. The small amount of...
Biochemical studies of phenylmercuric acetate (PMA) and
mercuric acetate toxicity in rats carried out during this investigation
were (1) the metabolism of ²⁰³Hg(Ac)₂ and ²⁰³Hg-PMA within kidney and liver tissues following oral
ingestion,
(2) the effect on some
soluble enzyme activities and determinations of ²⁰³Hg binding in the
enzyme fractions,...
An analytical technique has been developed for the determination of methylmercury compounds in environmental samples. The technique is based on a two-stage procedure. In the first stage, methylmercury compounds are isolated from the sample matrix as methylmercury chloride (MeRgCl) by distillation. The distillation procedure is based on a series of...
The simultaneous diffusion of Ca 2+ and Sr 2+ ions in purified
single crystals of KC1 and NaC1 was studied over the temperature
ranges from 451°C to 669°C in KC1 and from 448°C to 683°C in NaCl.
A radioactive tracer technique was used in two types of measurements:
diffusion from...
This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
A comparison was made of the d.c. conductivity of KCI:Pb²⁺
and KCl:PbO single crystals at temperatures greater than 325°C.
The energy of activation was 0.72 ev for all crystals. Lead concentration
was determined by chemical, optical and electrical methods. The
half band width of the UV absorption band at 273...
The analysis of the distribution of monoterpenes through the leaf pairs of a single shoot of Mentha piperita supports Reitsema's contention that the first terpenes formed are unsaturated ketones and that saturated terpenes are produced from these. The growth of Mentha piperita under varying conditions of temperature and the leaf-by-leaf...
Solubility studies on the heavy metal sulfides in liquid hydrogen
sulfide at room temperature were carried out using the isopiestic
method. The results were compared with earlier work and with a
theoretical result based on Raoult's Law. A relative order for the
solubilities of sulfur and the sulfides of tin,...
A simultaneous direct spectrophotometric method for the determination
of barium and strontium using Sulfonazo III has been developed
making use of the chelons EGTA and CDTA at controlled pH
values.
An absorbance study of the barium and strontium complexes of
Sulfonazo III revealed that there is no pH sensitivity of...
A study of the relative rates of benzylic hydrogen abstractions
from a series of meta and para substituted neopentylbenzenes by the
bromine radical and trichloromethyl radical at 70°C has been carried
out. Application of the Hammett equation yields p values of -0.75
for the bromine atom and -0.94 for the...
Inorganic structures play an important role in materials due to their versatility and diversity. A complete understanding of the structure of a material is vital to enhance the creation of new materials that fill voids in research. The rational design of these compounds is driven by the exploitation of structure-property...
Diffusion of short chain n-alkanes was found to be faster in the
polydimethylsilicone elastomer SE-30 than in the polydimethylsilicone
oil SF-96-2000. The opposite was true for the longer chain n-alkanes
suggesting that choice of stationary phase for gas chromatography
would depend on the chain length of sample components. The dependence...
The object of this investigation was to determine a number of
physical constants for the crystals of two commonly used insecticide
compounds. The compounds chosen were Aldrin and Dieldrin,
which are chlorinated cyclodiene compounds. These compounds are
in considerable use today, and show promise of heavy continued use.
The data...
A dual -pH simultaneous direct spectrophotometric method for
the determination of calcium and magnesium using Arsenazo III has
been developed.
An absorption spectra study was made of Arsenazo III and its
magnesium, calcium, strontium, and barium complexes at various
pH values. This study showed that total calcium and magnesium
can...
A systematic study of the elution of magnesium and calcium from
Dowex 50 X 8 resin using α-hydroxyisobutyric acid (α-HIBA) at
various pH values and concentrations, indicated that the difference in
the equilibrium distribution coefficients of these two elements was
large enough for a good separation. This fact was applied...