Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
The strained carbon ring, bicyclo[1.1.1]pentane, was synthesized by a reaction between
1-(phenylsulfanyl)bicyclo[1.1.1]pentane, prepared from propellane, and Raney nickel.
Infrared spectra were recorded at a resolution of 0.0015 cm-1, a resolution significantly
better than previous measurements, 0.06 cm-1. A single fundamental band was analyzed
to determine the ground state and excited...
Interesting rovibrational characteristics of two D_(3h) oblate symmetric top molecules were studied. Hamiltonian models for the fine rovibrational level structure of [1.1.1]propellane (propellane) were obtained for many low-lying modes. Ground state parameters (GSP) that are not exclusively K^(2n) dependent were obtained. Initially, the GSP were used in conjunction with density...
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Joseph W. Nibler
Interesting rovibrational characteristics of two D3h oblate symmetric
High resolution spectroscopy was used to study the properties of two simple polyatomic molecules, sulfur trioxide, SO₃, and carbon suboxide, C₃O₂. The fundamental modes and several hot bands of the ¹⁸O isotopic fonns of SO₃ (³²S¹⁸O₃ and ³⁴S¹⁸O₃) have been investigated using both infrared spectroscopy and coherent anti-Stokes Raman scattering...
The CARS apparatus at OSU was modified to permit studies in the 0-500 cm⁻¹ spectral region. The new low frequency capabilities were then used to study molecular clusters formed in free expansion jets of carbon dioxide. A strong cluster band was observed at 73 cm⁻¹, with a weaker shoulder at...
The two sulfur isotopomers of sulfur trioxide, ³²S¹⁶O₃ and ³⁴S¹⁶O₃, have been studied via high resolution infrared and Coherent anti-Stokes Raman (CARS) spectroscopy. The v₁ symmetric SO stretching Q-branches observed by the latter are quite different, being especially complex for ³²S¹⁶O₃ Understanding this band structure required analysis of infrared-active hot...
Ab initio calculations using the B3LYP and CCSD(T) methods were employed in this work to explore the most stable structure of the intriguing compound Be(BH₄)₂, for which as many as seven different structures have been proposed in the literature. Use of the B3LYP density functional method with several large basis...
Applications of several methods of coherent nonlinear Raman Spectroscopy have been made in this thesis research. The theory and potential of one of these, Photoacoustic Raman Spectroscopy (PARS), is discussed in chapter two. Experimental results are presented which illustrate the sensitivity of this method and establish sampling conditions for maximum...
Two nonlinear optical experiments are presented in which the third-order electronic susceptibility of molecules is used to generate Raman signals. The first one uses a single 532 nm beam from a Nd:YAG laser to produce Stimulated Raman Scattering in benzene and deuterated benzene. With a simple experimental set-up, stimulated emission...
The work presented in this thesis deals with the mechanisms by which a vibrationally excited diatomic molecule gives up its energy to a host monatomic lattice at low temperature. The vibrational lifetimes (v"=1) of the metal oxides Ba0 and A10 in their ground electronic states are studied using pulsed dual...
Due to its importance, the phenomenon of hydrogen
bonding has been the subject of much research over the
years. Among the different techniques used to study
hydrogen bonded systems, vibrational spectroscopy is
perhaps the most sensitive because of the striking
changes induced in molecular spectra by the formation of
hydrogen...
A new experimental apparatus was built at Oregon State University to perform high resolution stimulated Raman spectroscopy in a pulsed molecular jet at state densities of the order of 10¹¹ cm⁻³. The technique uses a stimulated Raman step to first populate a vibrational/rotational level and then a resonantly enhanced multiphoton...
This study identified new compounds with pest control activities. The two sources of candidates that were followed here were the main heartwood extract of Alaska Yellow Cedar (AYC) constituents and several semi-synthetic counterparts. Five compounds were isolated and identified for the first time in AYC heartwood in this research: two...
The high resolution stimulated Raman spectrometer at OSU was
modified to improve its sensitivity and to extend its range of
applications to low Raman shifts and to the spectroscopy of solids and
liquids. As part of the characterization of the spectrometer, optical
Stark effects on rotational and vibrational transitions of...
The techniques of coherent anti-Stokes Raman spectroscopy (CARS)
and inverse Raman spectroscopy (IRS) are used to examine carbon dioxide
aggregation in a supersonic jet expansion. To promote the formation of
small clusters, a BMW injector valve is modified to permit its use as a
pulsed nozzle at very cold temperatures....
Current studies suggest that perfluorinated organic compounds, such as fluorotelomer alcohols (FtOHs) in the troposphere, may be precursors of perfluorocarboxylic acids and perfluorosulfonates in remote regions. Fluorinated organic compounds were investigated in archived extracts collected from remote locations in Okinawa, Japan (HSO) and Mount Bachelor, Oregon (MBO) during the springs...
Structure-property relationships have always underpinned the field of solid state chemistry; dependable structural descriptions are integral to understanding and controlling the physical properties of inorganic compounds old and new. While a handful of crystal structures are celebrated for their versatility, flexibility, and functionality, the existence of more exotic structures is...
The velocity of sound in gases was measured, using an ultrasonic
wave train as a diffraction grating. The fundamental problems
involved in the optical technique are discussed. An apparatus utilizing
an objective lens of focal length 1.5 m and aperture f/20 was constructed
and used at an ultrasonic frequency close...
Lithium serves an unparalleled role for high energy-density storage applications and is vital for the continued advancement of the world economy. However, global supply is heavily reliant on lithium deposits situated in select locations, creating unpredictability in the price and concerns for the sustained production of the resource. Additionally, future...