The photoelectron spectra of a series of halogenated
molecules have been investigated in the gas phase. Both
core-ionization energies and Auger kinetic energies were
measured to probe the nature of the interaction that holds
a core electron to the molecule.
It was found that satellite structure (shake) could be
used...
The physical properties of hydrochloric acid and deuterium chloride were derived through the use of the harmonic oscillator and rigid rotor quantum mechanical models. By first obtaining angular momentum quantum values for HCl and DCl through Fourier Transform Infrared Spectroscopy, these two systems could be summed and processed with additional...
Significant figures have been a nebulous area in the physical sciences. The results of a literature survey, and of a questionaire distributed among the Chemistry Department faculty at Oregon State University, revealed widely differing interpretations regarding the proper role of significant figures. The present study has a two-fold nature. First...
Theoretical studies and experimental results are presented for the rotational motion of molecule's in crystalline solids. The group theory is solved for molecules of any symmetry matrix isolated at a site in a crystal field of any symmetry. As the potential terrier to rotation of the molecule relative to the...
A nonflame method for atomic absorption spectroscopy is
described. A helical tungsten filament from a commercially available
6-V, 4-A light bulb, heated to :incandescence in an argon atmosphere
is used to atomize 2-μl aqueous samples for metals analyses. Studies
of two hollow cathode lamp tungsten filament orientations, a
modulated light...