Index Catalog // ScholarsArchive@OSU

Creator:: Neyzari, Shahrokh Ghaffari
Abstract:: An automated multielement flame atomic fluorescence (AF) spectrometer based on microcomputer control was constructed to determine four elements simultaneously. The instrument employs a multiple exit slit monochromator where the light from various exit slits is directed to a single detector with a mirrored funnel. Each element is excited to fluoresce...
Resource Type:: Dissertation

Creator:: Xu, Wei
Abstract:: Novel graphite intercalation compounds (GICs) and associated chemistry have been explored, specifically: (1) containing alkyl- substituted imidazolium cations; (2) a series containing alkaline earth metal (Mg, Ca, Sr, Ba) cations with ethylenediamine (en) co-intercalates; (3) showing reversible intragallery M-M bonding and (4) via electrochemical intercalation of Mg cations with potential...
Resource Type:: Dissertation
Full Text:: 192 Ho 1470 2720 -2.33 192 Er 1522 2510 -2.33 189 Tm 1545 1727 -2.319 190 Yb 816 1193 -2.19 (-2.76

Creator:: Allen, Scott E.
Abstract:: A series of compounds, 7-8 and 20-25, were tested as competitive inhibitors of 2,5-dihydroxyacetanilide epoxidase I (DHAE I) and DHAE II. A Hammett plot was constructed for each enzyme to determine the effect of electron density on inhibition. DHAE I gave a linear, highly correlated plot (r²=0.91) that signifies the...
Resource Type:: Dissertation

Creator:: Yappert, Marta Cecilia
Abstract:: An instrument was constructed to measure molecular fluorescence (FL) or chemiluminescence (CL) and absorbance (ABS) simultaneously. The lower, middle, and upper portions of the test solution are probed to obtain ABS, FL, and CL data. Optical fibers are used extensively. The ABS and FL or CL spectra are acquired in...
Resource Type:: Dissertation

Creator:: Smith, Monty Ray
Abstract:: Instrumental and radiochemical neutron activation analyses supported by electron microprobe mineral analyses (Paul Warren, University of New Mexico) and petrographic observations are presented for approximately forty individual clasts separated from the Kapoeta howardite. These clasts are classified into eucritic, cumulate-like, mafic (plagioclase ± olivine-bearing pyroxenites), pyroxenite, polymict and/or metal-rich and...
Resource Type:: Dissertation
Full Text:: (n ,y)TmEu(EC) 152sm(n ,y)153Sm and 151Eu(n,y)152mEu(C)152Gd(no) 153Gd yiel ed specific activities

Creator:: Shaw, Subrata
Abstract:: This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
Resource Type:: Dissertation

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