Index Catalog // ScholarsArchive@OSU

New Graphite Intercalation Chemistry with Alkaline Earth Metals

Creator:: Xu, Wei
Abstract:: Novel graphite intercalation compounds (GICs) and associated chemistry have been explored, specifically: (1) containing alkyl- substituted imidazolium cations; (2) a series containing alkaline earth metal (Mg, Ca, Sr, Ba) cations with ethylenediamine (en) co-intercalates; (3) showing reversible intragallery M-M bonding and (4) via electrochemical intercalation of Mg cations with potential...
Resource Type:: Dissertation

Fundamental Studies of the Structure-Property Correlations of Na-ion and K-ion Storage in Non-Graphitic Carbon

Creator:: Li, Zhifei
Abstract:: Grid-scale energy storage systems are urgently needed to increase the flexibility and rigidity of the grid for modern society and take full advantage of the renewable green energy resources such as solar energy and wind energy. Na-ion batteries (NIBs) and K-ion batteries (KIBs) have been emerged as one of the...
Resource Type:: Dissertation

New Graphite Intercalation Chemistry with Ethers and Amines

Creator:: Zhang, Hanyang
Abstract:: Novel donor-typed ternary graphite intercalation compounds (GICs) are synthesized and characterized containing (1) pyrrolidinium cations with DMSO co-intercalates; (2) alkali metal cations with crown ether co-intercalates; and (3) alkali metal cations with polyethylene glycol co-intercalates. Structural and compositional data are obtained for the stable products. A new ether-amine co-intercalate exchange...
Resource Type:: Dissertation

New chemistry for electrochemical energy storage applications

Creator:: Wang, Xingfeng
Abstract:: Electrochemical capacitors and batteries are two major electrochemical energy storage technologies, which have been investigated extensively to meet the rapidly-growing demand for higher energy, higher power, lower cost and enhanced safety in the past few decades. With the charge storage mechanism of electrostatic charge adsorption desorption via electrical double layers,...
Resource Type:: Dissertation
Full Text:: ...............................................................................................67 5 New Redox Pair in Aqueous Electrolyte for EC Applications ............................ 75

Computational Investigation and Prediction of Mechanisms and Stereocontrol in Complex Organic Reactions

Creator:: Pattawong, Ommidala
Abstract:: Complex organic transformations, such as the addition of pyrrole to ketene using planar chiral organocatalyst (*PPY), the four-component anhydride- Manniach reactions, and the site-selective desymmetrization of meso-1,2-diol, are remarkable synthetic reactions that provide high yield and high selectivity. However, the exact mechanism and origins of stereocontrol for theses synthetic organic...
Resource Type:: Dissertation

Human exposure to polycyclic aromatic hydrocarbons : global cancer risk and metabolism

Creator:: Motorykin, Oleksii
Abstract:: In recent decades, there has been increased attention on human exposure to, and subsequently toxicity of, Polycyclic Aromatic Hydrocarbons (PAHs). PAHs are widespread organic pollutants and some have been shown to be toxic, carcinogenic and mutagenic. This research was focused on understanding the link between global PAH emissions and lung...
Resource Type:: Dissertation

The atmospheric chemistry of particulate-bound polycyclic aromatic hydrocarbons : concentration, prediction, laboratory studies, and mutagenicity

Creator:: Jariyasopit, Narumol
Abstract:: The trans-Pacific atmospheric transport of particulate matter (PM)-bound polycyclic aromatic hydrocarbons (PAHs) to remote sites in western North America has been well documented and has triggered research questions regarding to atmospheric transformation of PM-bound PAHs and the potential impacts on human health from their inhalation exposure. In this dissertation, field...
Resource Type:: Dissertation

Single crystal growth, powder synthesis and characterization of layered chalcogenide semiconductors

Creator:: Richard, Annette Pauline
Abstract:: This thesis presents basic studies, including structural, optical and transport measurements, on novel chalcogenide powders and single crystals. BiCuOSe crystals have been synthesized for the first time. The crystal structure of BiCuOSe has been refined and the optical band gap has been measured to be 0.83eV. Crystal structure refinements of...
Resource Type:: Dissertation
Full Text:: the p- type material to its respective conduction band, EC. As a result of the band bending, due

Large volume (1,800 µL) injection HPLC/MS/MS for the quantitative determination of illicit drugs and human urinary biomarkers in municipal wastewater

Creator:: Chiaia Hernandez, Aurea C.
Abstract:: A sensitive, selective, rapid analytical method based on large-volume injection (LVI) liquid chromatography/ tandem mass spectrometry was developed using commercially-available hardware that eliminates the need for either off-line or on-line solid phase extraction. Centrifugation followed by the direct injection of 1,800 µL was used for the quantification of illicit drugs,...
Resource Type:: Masters Thesis

A new trigonal huntite material and subgroup relationships between crystallographic space groups

Creator:: Hruschka, Michael Archimedes and Hruschka, Michael A.
Abstract:: The use of an adjacency matrix to determine distant (not maximal or minimal) subgroup and supergroup relationships between crystallographic spacegroup types is described. Full lists of space-group types that are supergroups and subgroups for every space-group type were compiled. A list of the space-group types connected to each space-group type...
Resource Type:: Dissertation

ScholarsArchive@OSU

New Graphite Intercalation Chemistry with Alkaline Earth Metals

Fundamental Studies of the Structure-Property Correlations of Na-ion and K-ion Storage in Non-Graphitic Carbon

New Graphite Intercalation Chemistry with Ethers and Amines

New chemistry for electrochemical energy storage applications

Computational Investigation and Prediction of Mechanisms and Stereocontrol in Complex Organic Reactions

Human exposure to polycyclic aromatic hydrocarbons : global cancer risk and metabolism

The atmospheric chemistry of particulate-bound polycyclic aromatic hydrocarbons : concentration, prediction, laboratory studies, and mutagenicity

Single crystal growth, powder synthesis and characterization of layered chalcogenide semiconductors

Large volume (1,800 µL) injection HPLC/MS/MS for the quantitative determination of illicit drugs and human urinary biomarkers in municipal wastewater

A new trigonal huntite material and subgroup relationships between crystallographic space groups

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