Index Catalog // ScholarsArchive@OSU

Chain extension of boronic esters with stereo- and regio-defined lithiated oxiranes

Creator:: Alwedi, Embarek
Abstract:: The stereospecific reagent-controlled homologation (StReCH) of boronic esters with putative lithiooxiranes generated in situ from appropriate precursors via sulfoxide-lithium exchange, tin-lithium exchange, and direct lithiation is described with an emphasis on the first lithiation technique which allows for the regio- and stereo-specific generation of all types of lithiooxirane isomer. Transient...
Resource Type:: Dissertation

Investigation of Chain Extension Approaches for the Stereoselective Reagent-Controlled Synthesis of alpha-Heteroatom Substituted Alkyl Boronic Esters

Creator:: Barsamian, Adam L.
Abstract:: Two distinct strategies were explored for the enantioselective synthesis of α-heteroatom substituted alkyl boronic esters by stereoselective reagent-controlled homologation using transient chiral carbenoid reagents CHYMX (Y = heteroatom, X = nucleofuge, M = electrofuge). In the first case, a stereospecific reagent-controlled homologation (sStReCH) approach to α-alkoxyalkylboronates using α-metalated S,O- and...
Resource Type:: Dissertation
Full Text:: Chemistry presented on September 3, 2015. Title: Investigation of Chain Extension Approaches for the

Gas-phase electron-diffraction investigations of, I. WF₆, ReF₆, OsF₆, IrF₆, PtF₆, O₂⁺PtF⁻₆, II. 3-aminoacrolein, III. 3-chloro-1-propanol, IV. 2,2',5,5'-tetramethyl-1,1'-distibacerrocene

Creator:: Richardson, Alan D.
Resource Type:: Dissertation
Full Text:: ₆, ReF₆, OsF₆, IrF₆, PtF₆, O₂⁺PtF⁻₆, II. 3-aminoacrolein, III. 3-chloro-1-propanol, IV. 2,2',5,5

Studies of low melting 1-methyl-3-ethylimidazolium chlorocuprate(I) fused salts

Creator:: Bolkan, Steven A.
Resource Type:: Dissertation
Full Text:: Studies of Low Melting 1-Methyl-3-ethylimidazolium

Investigation of the complexes of 3-(2-arsonophenylazo)-4,5-dihydroxy-2, 7-naphthalenedisulfonic acid, "arsenazo," with alkaline earths

Creator:: Warren, Herbert Dale
Resource Type:: Dissertation
Full Text:: Investigation of the complexes of 3-(2-arsonophenylazo

An approach to the morphine alkaloids : synthesis of 9-methoxy-3-methyl-2,3,4,4a,5,6-hexahydro-1H-benzofuro[3,2-e]isoquinoline-7(7aH)-ones

Creator:: Weller, Doreen L.
Resource Type:: Dissertation
Full Text:: from pyridine. Extension of this methodology to the preparation of 43 required the synthesis of the 3

Part I : synthesis of azetidin-2-ones from pyrazolidin-3-ones ; Part II : synthesis of a subunit of the immunosuppressant FK-506

Creator:: Toske, Steven Gerald
Resource Type:: Dissertation
Full Text:: Part I : synthesis of azetidin-2-ones from pyrazolidin-3

Prediction and Measurement of Polycyclic Aromatic Hydrocarbons (PAHs) Transformation Products in the Environment.

Creator:: Titaley, Ivan A.
Abstract:: Polycyclic aromatic hydrocarbons (PAHs) are a group of environmental contaminants consisting of fused benzene rings. Parent-PAHs, methylated-PAHs (MPAHs), and PAHs with molecular weight of 302 a.m.u (MW302-PAHs) are considered as unsubstituted-PAHs. These unsubstituted-PAHs undergo transformation reactions resulting in the formation of PAH-transformation products (PAH-TPs), or substituted-PAHs, including nitrated-, oxygenated-, and...
Resource Type:: Dissertation
Full Text:: the results from manual analysis to benchmark OCTpy’s effectiveness in data analysis time savings

Conformation and reactivity studies of some bicyclo(3.3.1) nonane derivatives

Creator:: Sturmer, David Michael
Abstract:: New syntheses for 2-bicyclo(3.3.1)nonanone and 7-bicyclo-(3.3.1)nonen-2-one were developed. The saturated ketone was prepared from phenol and acrylonitrile via a novel intramolecular S[subscript N]2 cyclization process. A Friedel-Crafts cyclization of 3-(3-cyclohexenyl)propanoyl chloride permitted synthesis of the unsaturated ketone from 4-cyclohexene carboxaldehyde. The formation of the bicyclo(3.3.1)nonane rather than a bicyclo(3.2.2)nonane skeleton...
Resource Type:: Dissertation
Full Text:: REACTIVITY STUDIES OF SOME BICYCLO(3. 3. 1)NONANE DERIVATIVES Abstract approved (Major professor) New

Aqueous chemistries for oxide electronics

Creator:: Meyers, Stephen T.
Abstract:: The variegated aqueous chemistries of metal cations are applied to the design and synthesis of non-toxic solution precursors suitable for additive printing of large-area oxide electronics. Polycondensation behaviors of aqueous Al+3 and PO4 +3 are manipulated in the deposition of atomically smooth amorphous aluminum oxide phosphate (AlPO) dielectric films. AlPO...
Resource Type:: Dissertation
Full Text:: behaviors of aqueous Al +3 and PO4 +3 are manipulated in the deposition of atomically smooth amorphous

ScholarsArchive@OSU

Chain extension of boronic esters with stereo- and regio-defined lithiated oxiranes

Investigation of Chain Extension Approaches for the Stereoselective Reagent-Controlled Synthesis of alpha-Heteroatom Substituted Alkyl Boronic Esters

Gas-phase electron-diffraction investigations of, I. WF₆, ReF₆, OsF₆, IrF₆, PtF₆, O₂⁺PtF⁻₆, II. 3-aminoacrolein, III. 3-chloro-1-propanol, IV. 2,2',5,5'-tetramethyl-1,1'-distibacerrocene

Studies of low melting 1-methyl-3-ethylimidazolium chlorocuprate(I) fused salts

Investigation of the complexes of 3-(2-arsonophenylazo)-4,5-dihydroxy-2, 7-naphthalenedisulfonic acid, "arsenazo," with alkaline earths

An approach to the morphine alkaloids : synthesis of 9-methoxy-3-methyl-2,3,4,4a,5,6-hexahydro-1H-benzofuro[3,2-e]isoquinoline-7(7aH)-ones

Part I : synthesis of azetidin-2-ones from pyrazolidin-3-ones ; Part II : synthesis of a subunit of the immunosuppressant FK-506

Prediction and Measurement of Polycyclic Aromatic Hydrocarbons (PAHs) Transformation Products in the Environment.

Conformation and reactivity studies of some bicyclo(3.3.1) nonane derivatives

Aqueous chemistries for oxide electronics

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