Index Catalog // ScholarsArchive@OSU

Insights and Patterns from Quantitative and Statistical Analyses of Chemical Systems

Creator:: Grove, Markas Albert
Abstract:: The work presented here is the culmination of efforts in describing complex chemical systems with statistical methods, thereby providing relatively simple quantitative models and easily comprehensible qualitative insights. The following investigations have various goals, such as development of new methods, fundamental understanding, molecular control of chemical species, and advancement of...
Resource Type:: Dissertation
Full Text:: Albert Grove for the degree of Doctor of Philosophy in Chemistry presented on August 20, 2020

Structural Elucidation of Metal-Oxo Systems by X-Ray Scattering Methods

Creator:: Kozma, Karoly
Abstract:: Metal-oxo clusters are discrete molecular metal-oxides. Most metals form numerous cluster compounds that can be ligated, unligated, charged or neutral, controlling their solubility in water and/or organic solvents. They are important species to study reaction pathways from the monomeric building units to the bulk metal oxides, and have many application...
Resource Type:: Dissertation

Substitutional Effects on the Electromechanical Properties of Lead-free, Piezoelectric (Na₀.₅Bi₀.₅)TiO₃-BaTiO₃ (NBT-BT)

Creator:: McQuade, Ryan R.
Abstract:: This work investigates the effect of cation substitution on the properties of the lead-free, solid solution (Na₀.₅Bi₀.₅)TiO₃-BaTiO₃ (NBT-BT). Substitution into NBT-BT increases disorder and increases the relaxor ferroelectric properties. These relaxor ferroelectric materials show large piezoelectric strains that can be utilized in actuator applications. Ceramic samples were prepared using standard...
Resource Type:: Dissertation
Full Text:: present. In particular, Wesley Surta, Dylan Fast, Thomas Rowe, and Charles Culbertson, Alyssa Johnson

Precursor Chemistry and Film Structure and Properties via Solution Deposition

Creator:: Huang, Yu
Abstract:: Chemistry of preparing dense film from solution deposition is explored with several cases in this thesis. Surface dense structure, conversion at melting point, and ion exchange in aqueous solution are the main topics covered here for the thin films of aluminum oxide phosphate and tin dioxide. Thin film density, optical...
Resource Type:: Dissertation

The kinetic and radiolytic aspects of control of the redox speciation of neptunium in solutions of nitric acid

Creator:: Precek, Martin
Abstract:: Neptunium, with its rich redox chemistry, has a special position in the chemistry of actinides. With a decades-long history of development of aqueous separation methods for used nuclear fuel (UNF), management of neptunium remains an unresolved issue because of its not clearly defined redox speciation. Neptunium is present in two,...
Resource Type:: Dissertation

Structure-property relationships of layered oxypnictides

Creator:: Muir, Sean W.
Abstract:: Investigating the structure-property relationships of solid state materials can help improve many of the materials we use each day in life. It can also lead to the discovery of materials with interesting and unforeseen properties. In this work the structure property relationships of newly discovered layered oxypnictide phases are presented...
Resource Type:: Dissertation
Full Text:: different compositions are known [5]. The ZrCuSiAs structure as first reported by Johnson and Jeitschko

A Diels-Alder approach to biaryl synthesis

Creator:: Ashburn, Bradley O.
Abstract:: An expedient approach to the synthesis of a wide range of highly programmable biaryl templates has been accomplished. Utilizing the Diels-Alder [4+2] cycloaddition, a wide range of tri- and tetra-ortho-substituted biaryls have been synthesized in only three to four steps from commercially available materials. We have successfully synthesized entire classes...
Resource Type:: Dissertation
Full Text:: , D. A.; Bourne, G. T.; Smythe, M. L. Chem. Rev. 2003, 103, 893. (b) Lesuisse, D.; Albert, E

Analysis of semi-volatile organic contaminants and their accumulation in remote aquatic ecosystems of the western US

Creator:: Ackerman, Luke K.
Abstract:: Many pesticides, polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), and polycyclic aromatic hydrocarbons are persistent, bio-accumulative, and toxic. These semi-volatile organic compounds (SOCs) can undergo atmospheric transport and deposition in cold, remote ecosystems. A better understanding of their accumulation in the fish of these ecosystems is important to better predict...
Resource Type:: Dissertation
Full Text:: me grow, learn, and accomplish, my scholarly mentors Debbi Woodard and Lynn MacAusland, Fr. Michael

Novel approaches to enhancing selectivity and efficiency in microscale liquid chromatography

Creator:: Vallano, Patrick T.
Abstract:: For a number of reasons, miniaturization of chromatographic columns has been a general trend over the past three decades. Methods designed to enhance selectivity and efficiency can offer improved separation power and speed, expanding on the advantages of miniaturized columns. This dissertation describes novel approaches in this direction, focusing on...
Resource Type:: Dissertation

Development of new data collection and analysis techniques for low energy electron diffraction and their application to the Mo(110)-p(2x2)-S and Al₂O₃ (0001) systems

Creator:: Toofan, Jahansooz
Resource Type:: Dissertation

ScholarsArchive@OSU

Insights and Patterns from Quantitative and Statistical Analyses of Chemical Systems

Structural Elucidation of Metal-Oxo Systems by X-Ray Scattering Methods

Substitutional Effects on the Electromechanical Properties of Lead-free, Piezoelectric (Na₀.₅Bi₀.₅)TiO₃-BaTiO₃ (NBT-BT)

Precursor Chemistry and Film Structure and Properties via Solution Deposition

The kinetic and radiolytic aspects of control of the redox speciation of neptunium in solutions of nitric acid

Structure-property relationships of layered oxypnictides

A Diels-Alder approach to biaryl synthesis

Analysis of semi-volatile organic contaminants and their accumulation in remote aquatic ecosystems of the western US

Novel approaches to enhancing selectivity and efficiency in microscale liquid chromatography

Development of new data collection and analysis techniques for low energy electron diffraction and their application to the Mo(110)-p(2x2)-S and Al₂O₃ (0001) systems

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