This paper describes the synthesis of t-butyl bicyclo[7.1.0]
decane-2-percarboxylate and its photolytic decomposition. The title
compound was found to undergo simple homolytic cleavage when exposed
to light of 2537 A; producing the cyclodecyl radical, carbon dioxide,
and t-butoxy radical. The largest percentage of products arose from
an intimate radical pair...
Grid-scale energy storage systems are urgently needed to increase the flexibility and rigidity of the grid for modern society and take full advantage of the renewable green energy resources such as solar energy and wind energy. Na-ion batteries (NIBs) and K-ion batteries (KIBs) have been emerged as one of the...
Dearomatization reactions exist broadly in biosynthesis and chemical synthesis. The highly functionalized atoms of arenes can be masked by it aromaticity, and upon dearomatization, those reactive atoms can be readily applied to bond formation and further manipulation. The total synthesis of (–)-cephalotaxine and (–)- homoharringtonine is described via an oxidative...
A study of the relative rates of the alkyl hydrogen abstraction
from a series of meta and para substituted t-butylbenzenes by the
chlorine atom at 70°C has been carried out. Application of the
Hammett equation yielded a ρ value of -0.44 for the para compounds.
Possible explanations for the non-linearity...
We have developed a compact micro total analysis system (μTAS) to serve as a platform for in-situ spectrophotometric water quality monitoring. Individual fluidic, optical, and electrical components were designed, developed, and characterized. These components were combined in both an integrated (single lithographic “chip-based” platform) and a modular manner. The microfluidic...
An intermediate of oxidative phosphorylation was apparently
solubilized from cabbage mitochondria. The method of solubilization
used primarily was extraction of a mitochondrial acetone powder
with 0.1 M glycylglycine, pH 7.4, at 4° C. The intermediate
betrayed its presence by causing the transfer of Pi³² to ADP with
the resultant formation...