Both oxy-Cope and siloxy-Cope rearrangements involve
(1, 3) and (3, 3) sigrnatropic shifts. Both the concerted mechanism,
and the stepwise mechanism via a diradical intermediate are possible.
In a cyclic system such as cis-l-vinylcyclooct-3-en-l-ol, the thermal
rearrangement takes place preferably through a diradical intermediate.
At high temperature, the reaction also...
PART I. A chemical examination of the materials toxic to fish in
kraft pulp mill wastes has been made as part of a water pollution
study. Thirty gallons of "foul condensate" from a typical kraft mill
gave 14 g of organic material when extracted with methylene chloride,
and an additional...
This dissertation outlines two approaches for improving the efficiency and reducing the cost of photovoltaic energy generation. First, the structures of known binary copper and iron compounds are used to choose the promising compositions Fe₂XS₄ (X = Si, Ge), Cu₃TaQ₄ (Q = Se, Te), and BaCuQ'F (Q' = S, Se,...
The dyeing of paper is one of the most important
processes in the manufacture of that material. Fully 95 percent
of the paper that is produced is colored to a greater or
lesser extent, and in many eases the reproduction of a shade
is essential. That pH is an important...