Levels of activity of glucose-6-phosphate- , 6-phosphogluconate- , and isocitric- dehydrogenase were measured in the
soluble and particulate fractions of heart, brain and liver at
several ages throughout the development of the chick embryo.
Compared to isocitric dehydrogenase, levels of glucosesphosphate-
, and 6-phosphogluconate- dehydrogenase are generally
low. This suggests...
In an attempt to find a laboratory species which develops an
experimental myopathy similar to white muscle disease (WMD) in
lambs, comparative studies of nutritional muscular dystrophy of
chicks were initiated. This condition was grossly visible as white
striations running parallel with the fibers of the pectoral muscles and
was...
Bicyclo [6.1.0] non-4-ene was prepared by two routes; (1) reaction
of cis-cis-1, 5-cycloöctadiene with methylene iodide and zinc-copper
couple, (2) sodium-methanol reduction of 9, 9-dibromobicyclo-[6.1.0] non-4-ene. The bicyclononene was characterized by its infrared
spectrum, nuclear magnetic resonance spectrum and common
physical properties. The olefin was hydrogenated to bicyclo [6.1.0] -...
The methanolysis of phosphorus trichloride coordinated to nickel
(0) has been studied. Free phosphorus trichloride reacts with methanol
to give dimethyl hydrogen phosphonate, methyl chloride, and hydrogen
chloride. The reaction involves a rearrangement on phosphorus using
the lone pair, in which the coordination number increases from three
to four. In...
Steroid carbenes have been investigated as synthetic intermediates.
Basic decomposition of 4-en-3-one tosylhydrazones (and
other A-ring systems) gives varying amounts of 2, 4-dienes, and
solvent derived products with diglyme, heptane, tetrachloroethylene,
carbon tetrachloride, benzene and cyclohexene. A method for
separating complex product mixtures was developed and a study of
the...
Dihalocarbenes have been generated mainly by thermal decomposition
of sodium trihaloacetate and phenyl (trihalomethyl)mercury,
and give gem-dihalocyclopropyl adducts with various steroid olefins.
A new procedure involving the use of sealed tubes makes possible the
addition of dihalocarbenes to sterically hindered olefins. In this manner,
7-cholestenyl benzoate when treated with PhHgCC1₃...
A specially designed gas chromatograph with both TCD and FID has
been tested for the measurement of the diffusion coefficients of methane and propane in helium. Knox's arrested elution technique(⁴) was used and yielded a value of 0.6431 cm²/sec averaged with the value
obtained by Yang and Hawkes(⁷). Values of...
A double-beam photometer was designed and built employing photon counting to give a direct digital readout. It was evaluated as an analytical instrument with special emphasis on pulse recovery time, pulse interaction and instrument settings. An equation is developed to explain pulse interaction in event counting systems.