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Derivation of Halide Bond Lengths through Fourier Transform Infrared Spectroscopy

Creator:

Gonzales, Seth

Abstract:

The physical properties of hydrochloric acid and deuterium chloride were derived through the use of the harmonic oscillator and rigid rotor quantum mechanical models. By first obtaining angular momentum quantum values for HCl and DCl through Fourier Transform Infrared Spectroscopy, these two systems could be summed and processed with additional...

Resource Type:

Research Paper

Full Text:

rotational quantum number (J=0,1,2…); and 𝐼! is the moment of inertia, which is shown to be
High-resolution infrared studies of perdeutero-spiropentane, C₅D₈

Creator:

Erickson, Blake Alexander, Ju, X., Nibler, Joesph W., Beaudry, C. M., and Blake, T. A.

Abstract:

Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...

Resource Type:

Article

Full Text:

Number of text pages: 20 Number of Tables: 3 Number of Figures: 4