A spectrophotometric study has been made of catalysis of the decomposition of sulfuryl chloride in carbon tetrachloride solution to an equilibrium mixture of sulfuryl chloride, sulfur dioxide and chlorine. The catalysts were activated charcoal, acetonitrile and 18-crown-6 polyether. A weak acetonitrile-sulfur dioxide complex also was established; formation constants found at...
Perdeutero-spiropentane (C₅D₈) has been synthesized and infrared and Raman spectra are reported for the first time. Wavenumber assignments are made for most of the fundamental vibrational modes. Gas phase infrared spectra were recorded at a resolution (0.002 cm⁻¹) sufficient to resolve individual rovibrational lines and show evidence of strong Coriolis...
This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...