The methanolysis of phosphorus trichloride coordinated to nickel
(0) has been studied. Free phosphorus trichloride reacts with methanol
to give dimethyl hydrogen phosphonate, methyl chloride, and hydrogen
chloride. The reaction involves a rearrangement on phosphorus using
the lone pair, in which the coordination number increases from three
to four. In...
Understanding structural evolution in solids as composition changes is essential to materials properties prediction. Such structure-properties relationships are the theme of solid state chemistry. Materials scientists and chemists have utilized an abundance of simple crystal structures to enhance understanding of chemical and structural origins of properties in materials for decades....
The spin-orbit states of both the ground and several
charge-transfer-excited electronic configurations of
gaseous MnX₂, CoX₂, NiX₂, and CuX₂ are derived. Only one-electron
transitions from the ground electronic state are
considered. The molecules are treated as linear in both
the ground and excited states. In each case, the spin-orbit
states...
Studies were undertaken to determine the extent and rate of
binding of Hg-203 labeled phenylmercuric acetate and mercuric ace
tate in rat kidney and liver slices and their subcellular fractions
after 37°C incubation of the slices in Krebs-Ringer -phosphate solutions
containing the mercurials at 10⁻⁴ molar. A fast and parallel...