Instrumental and radiochemical neutron activation analyses supported by electron microprobe mineral analyses (Paul Warren, University of New Mexico) and petrographic observations are presented for approximately forty individual clasts separated from the Kapoeta howardite. These clasts are classified into eucritic, cumulate-like, mafic (plagioclase ± olivine-bearing pyroxenites), pyroxenite, polymict and/or metal-rich and...
Major and minor minerals have been separated from
three L-6 chondritic meteorites (Alfianello, Colby (Wisconsin),
and Leedey). Olivine, hypersthene, diopside, feldspar,
troilite, chromite, phosphate minerals, and metallic
minerals were analyzed for major, minor and trace elements
using instrumental neutron activation analysis and radiochemical
neutron activation analysis techniques. Concentrations
df the...
The primary focus of this work is on examining structure-property relationships of interest for high-power nonlinear optical and laser crystals. An intuitive and simply illustrated method for assessing the nonlinear optical potential of structurally characterized noncentrosymmetric materials is introduced. This method is applied to materials including common quartz and tourmaline...
An expedient approach to the synthesis of a wide range of highly programmable biaryl templates has been accomplished. Utilizing the Diels-Alder [4+2] cycloaddition, a wide range of tri- and tetra-ortho-substituted biaryls have been synthesized in only three to four steps from commercially available materials. We have successfully synthesized entire classes...
In 1959 Kitagawa discovered and isolated the amino acid,
canavanine. Since its discovery much interest has been centered on
this amino acid because of its biological aspects; e.g. canavanine has
been shown to inhibit the growth of bacteria, viruses, protozoa, and
cancer cells.
The occurrence of canavanine is widespread in...
An automated instrument based on a single-board microcomputer
was developed for use in voltammetric analyses. Operator input of
numerous experiment parameters allows any type of voltammetric
analysis to be implemented and multiple scans to be run unattended.
A three operational amplifier potentiostat is used to control
the cell voltage and...
An atmospheric pressure argon glow discharge is shown
to detect trace levels of carbohydrates in aqueous flowing
systems, using either of two glow discharge solution
interface configurations. The first configuration consists
of an oscillating glow discharge sustained between a flowing
aqueous cathode and platinum anode. Picomole and micromolar
mass and...
Aromatic heterocycles are core structural motifs in natural products, pharmaceuticals and biological polymers. Indoles, in particular, represent a significant subclass of aromatic heterocycles, both in terms of sheer numbers, but also in biological and pharmaceutical relevance. As such, new methodologies for the synthesis of indoles represent an important and continually...