At liquid nitrogen temperature the spectra of sublimed
films of NH₄NCS, both as phase I (the usual form stable at
room temperature) and phase II (the low temperature form),
exhibit detail usually reserved for gases at low pressures.
In both phases the symmetry of ammonium ion has degenerated
from tetrahedral...
The tosylhydrazones of 2-heptanone, 4,4-dimethy1-2-
heptanone, 6-heptyn-2-one and 4,4-dimethy1-6-heptyn-2-
one were synthesized and decomposed under a variety of
reaction conditions: dry lithium and sodium salt pyrolyses,
sodium methoxide thermolyses in diglyme and photolyses of
the lithium salt in tetrahydrofuran. The saturated analogues
2-heptanone tosylhydrazone and its 4,4-dimethyl
isomer afforded the...