Atomically-thin graphene sheets have unprecedented characteristics for biosensing applications. These characteristics include mechanical flexibility and strength, optical transparency, electrical sensitivity and biocompatibility. The primary theme of this dissertation is the characterization and application of graphene field-effect transistors (FETs) in biologically-relevant physiological environments.Understanding the interface that forms between an electrolyte and...
Despite climate change requiring the cutback of fossil fuel consumption, the world continues to increase its energy demands each year. To meet the ambitious goals outlined during the Paris Agreement in 2015, which set a goal to limit global warming to 1.5°C [1], changes in energy production methods are necessary....
The continuous development of higher performing battery materials has emerged in parallel with the development of new manufacturing processes. Nanomaterials are one solution to addressing the cycling and performance challenges that limit existing battery cells. However, many of the methods used today for nanomaterial synthesis are high temperature batch methods...
The aim of this work was to assess the viability of duplex stainless steel 2205 components built via selective laser melting for seawater applications. First, a comprehensive additive manufacturing assessment was done. The duplex stainless steel 2205 components were selectively laser melted from gas atomized powder (D90 <45m) using a...
Electrodeposition is a versatile polymer deposition technique to create nano-microscale materials using an electrical field generated from a charged droplet of solution and a grounded collector. Electrospinning or electrospraying can occur during electrodeposition, leading to the creation of nanofibers or bead-like materials depending on the process parameters. Photopolymerization of the...
Lead zirconate titanate (PZT) is the dominant ferroelectric material in the market due to its excellent piezoelectric properties, relatively high Curie transition temperature (T[subscript C]), low cost, etc. However, because of emerging applications with requirements for high temperature (T[subscript C] > 400 °C) ferroelectrics, researchers are increasingly looking at alternative...
Piezoelectric materials have been widely used in electromechanical actuators, sensors, and ultrasonic transducers. Among these materials, lead zirconate titanate Pb(Zr[subscript 1‐x]Ti[subscript x])O₃ (PZT) has been primarily investigated due to its excellent piezoelectric properties. However, environmental concerns due to the toxicity of PbO have led to investigations into alternative materials systems....
The amorphous to crystalline phase change is of great interest for the production and operation of phase change memory and germanium electronic devices. Phase change memory relies on the ability to differentiate between differences in optical or electrical properties between the amorphous and crystalline phases of a single material. Amorphous...
It has been well established that ferroelectric to relaxor crossover in piezoelectric ceramics exhibit promising electromechanical and dielectric properties over a wide temperature range, applying sensors and actuators transducers and such. A plethora of research has reported giant strain in various lead-free piezoelectric ceramics and attributed the reasoning to the...
Aerogels are interesting material systems with outstanding properties such as low density, high surface area, and low thermal conductivity. They can be used for a variety of applications, such as solar cells, sensors, or catalysts. Additionally they provide a unique model system to study the properties of small particles. Cellulose...