Organic semiconductors are used in a wide variety of applications including transistors,solar cells, and light emitting diodes. These materials are solution-processable,low cost, and tunable. Many successful organic optoelectronic materials utilizeblends of several types of molecules (such as donors and acceptors) in order topromote charge generation. As blends are an inherently...
This project investigated transient photoconductivity in organic donor-acceptor (D-A) systems, where a flourinated anthradithiophene, ADT-TES-F, acts as the donor. Various acceptor molecules were used, with different sidegroups, and different HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) energy level offsets relative to the acceptor. Thin film composites...
We measure the charging and discharging of two organic materials, PCBM and ADT-TES-F. These materials are studied through the noncontact method of particle trapping known as Optical Tweezers, where an IR laser is used to constrain the motion of a coated or noncoated silica sphere while its positional data is...
The continued development of organic semiconductor materials relies on an understanding of the relationship between optoelectronic properties, molecular structure, and molecular interaction. Several detailed studies of electronic properties in functionalized polyacene materials are presented. A computational model which allows the extraction of charge generation and transport properties from experimental data...
This work aims to broaden use of the organic semiconductor pentacene (Pn) by means of improving its oxidation and photodimerization stability. In particular, we study the photophysical properties of functionalized Pn derivatives with side groups R in amorphous thin film, referred to as Pn-R-F8 when fluorinated. Using the optics experiments...
Nuclear fusion reactors comprise a significant field of study due to their potential to provide a limitless, clean, and sustainable source of energy. The inertial electrostatic confinement fusor is a type of fusion-generating device that accelerates deuterium gas to the conditions required for fusion. The goal of this research was...
Studies of light-matter interactions in organic semiconductors and in optical tweezer trapping of nanoparticles are presented. In the research related to organic semiconductor materials, a variety of novel materials and their composites have been characterized, and physical mechanisms behind their optoelectronic properties have been established. Three novel functionalized hexacene derivatives...
I led a collaborative project involving a search for an evidence of a gravitational wave background (GWB) with all the spatial correlations allowed by general metric theories of gravity using NANOGrav’s 12.5 year data set. The search found no substantial evidence in favor of the existence of such correlations.
The...
Organic semiconductors have attracted considerable attention due to their applications in low-cost, solution-processable (opto)electronic devices. An important class of high-performance organic semiconductors is pentacene derivatives, which exhibit high charger carrier mobilities in field-effect transistors and ultrafast singlet fission in photovoltaic devices. These derivatives have served as benchmark materials for systematic...
The utility of high-throughput, computational screening has become an invaluable asset to the field of materials science. In the hierarchy of computational methods, the most accurate methods are often the most computationally expensive. However, as both the efficiency and fidelity of numerical techniques advance, high-quality screening of large materials datasets...