Three approaches toward the core of halichlorine and pinnaic acid are described. The first approach entails a racemic transannular nitrone-olefin [3+2] cycloaddition from nitrone 238. Construction of the nitrone 238 began with aldehyde 241. Another key feature in this route involved a ring-closing metathesis for the formation of a 14-membered...
Most students arrive at game-focused physical education (PE) with neither the skills nor the tactical knowledge to be successful (Metzler, 2000). Although the Teaching Games for Understanding (TGFU) approach can enhance both on- and off-the-ball skills in game play performance (Griffin et al., 1995; Harvey et al., in review, Harvey...
This dissertation investigates the relative importance of firm-specific and
geographic characteristics for export behavior in the Chilean primary and processed
food industries. The first essay develops a new method for measuring geographic
characteristics to account for economic activity in adjacent, but separate spatial units.
In the application to the Chilean...
Wildlife managers are on the front lines of the effort to conserve wildlife and
are required to do so cost-effectively. This dissertation consists of three manuscripts
that integrate economics and ecology to inform cost-effective wildlife management.
The first and second manuscripts focus on identifying cost-effective wildlife
management plans. The third...
Authentication protocols play important roles in network security. A variety of authentication protocols ranging from complex public-key cryptosystems to simple password-based authentication schemes have been proposed. However, currently there is no fully secure authentication scheme that can resist all known attacks. When a user authentication is performed over an insecure...
Multiple-input multiple-output (MIMO) antenna technology is promising
for high-speed wireless communications without increasing the transmission band-
width. Space time coding (STC) is a scheme that employs multiple antennas to
increase transmission rate or to improve transmission quality. STC is used widely
in mobile cellular networks, wireless local area networks (WLAN)...
Our view of phytoplankton has historically revolved around their inability to
control their location in space. The term phytoplankton itself underscores this
particular difference between phytoplankton and their sessile terrestrial counterparts.
Yet there are other differences between land plants and the phytoplankton that are
perhaps equally important, beyond this sessile-planktonic...
In this thesis, I studied the translation of dengue virus RNA using a luciferase reporter gene system in Vero cells. The dengue reporter mRNA construct, which harbors 5´-terminal viral nts and 3´-terminal nts, could be translated efficiently compared to an alpha globin reporter construct. The 5´-cap structure and 3´-untranslated region...
The enzymes of dNTP synthesis in T4 infection associate to form a multienzyme complex, the T4 dNTP synthetase complex, facilitating the flow of metabolites en route to dNTPs, and their subsequent flow into DNA. Study of protein-protein interactions helps one to understand how the enzymes in the complex are organized...
Each year an estimated one million young women in the United States develop an eating disorder. Without early recognition of symptoms and early intervention/treatment, these eating disorders can lead to a host of chronic and debilitating illnesses.
Tooth erosion is one of the first signs of an eating disorder, providing...
Software maintenance accounts for a large portion of the software development cost, particularly the process of updating programs either to adapt for requirement change or to enhance design or efficiency. Currently, program updates are generally performed manually by programmers using text editors. This is an unreliable
method because syntax and...
Stable expression of transgenes is required for commercial uses of genetically engineered trees. To better understand the stability of transgene expression under field conditions, we studied transgene expression and RNA interference (RNAi)-induced transgene suppression in 2,480 transgenic poplars (460 transgene insertion events) over three years. Stability of expression was assessed...
Orthogonal frequency division multiplexing (OFDM), which has been very attractive for future high rate wireless communications, is very robust to channel multipath fading effect while providing high transmission data rate with high spectral efficiency.
Multiple antennas can be combined with OFDM to increase diversity gain and to improve spectral efficiency...
The 2004 Indian Ocean tsunami raised concern among marine park managers and
hazard mitigation professionals about the significant impact of major coastal hazards
on marine park natural resources and ecosystems. The main reason for this concern is
the strong linkage of marine parks and their rich assortment of ecosystem services...
We evaluated the regeneration behavior and early growth rates of 10 non-pioneer canopy tree species in medium-height, semi-evergreen dry tropical forest in Quintana Roo, Mexico. These species provide timber and non-timber forest products for local communities and include evergreen and deciduous species with varied dispersal mechanisms. The species were Coccoloba...
With 97% of the world’s freshwater resources stored underground, the connection between groundwater resources to the metrics of space, scale and time common to the geographic study of natural resources has not been extensively investigated by geographers. While nearly 240 transboundary aquifers are mapped across the world, a potential “tragedy”...
This thesis considers one of the classical problems in the actuarial mathematics literature, the decay of the probability of ruin in the collective risk model. The
claim number process N(t) is assumed to be a renewal process, the resulting model
being referred as the Sparre Andersen risk model. The inter-claim...
Plate boundaries are commonly regions of complex, diffuse deformation with
the motion across the boundary accommodated by numerous structural systems, rather
than being narrow, discrete zones of deformation. One such boundary occurs where
the North American plate makes contact with Juan de Fuca, Gorda, and Pacific plates
along the west...
The mathematical and physical connections between three different ways of quantifying linear predictability in geophysical fluid systems are studied in a series of analytical and numerical models. Normal modes, as they are traditionally formulated in the instabilities theories of geophysical fluid dynamics, characterize the asymptotic development of disturbances to stationary...
Fuel management has been used as an effective local strategy to reduce the undesirable consequences of wildfires. Many efforts toward scheduling of fuel management activities across a broader landscape have been proposed, with the hope of achieving larger landscape-scale management effects. However, scheduling of fuel management treatments across the broader...