Enantioenriched sp³-hybridized carbenoid reagents CR1R2MX (X = nucleofuge, M = electrofuge) of different types were investigated for the synthesis of polysubstituted alkyl chains by iterative stereospecific reagent-controlled homologation (StReCH) and for the stereospecific connective synthesis of alkenes by eliminative cross-coupling.
In the first part, putative enantioenriched α-chloroalkyllithiums (CHRLiCl) were employed...
Several new solid-state inorganic borates have been prepared and
characterized. Single crystals of the simple orthoborate ScB0₃ were
grown and its structure was determined by single-crystal X-ray
methods. The new borates Li₃Sc(B0₃)₂, LaSc₃(B0₃)₄, NdSc₃(B0₃)₄,
SrNaB0₃, and Li4Ln4MB90₂₃ (Ln = Y, Er, and Gd; M = Al and Ga) were
identified...
The
purpose
of
this
study
was
to
characterize
the
neutral
lipids
of
the
fat
body
of
the
larva
of
the
fleshfly
Sarcophaga
bullata
and
to
examine
the
means
by
which
these
lipids
are
synthesized.
The
weight
of
the
larva,
the
fat
body
as
well
as
its
lipid
content
were
examined...
Messenger RNA (mRNA) therapy has massive potential to treat various genetic disorders by providing effective proteins to the diseased cells and tissues. Its therapeutic applications include protein replacement, genome editing, and immunotherapy. For successful mRNA treatment, mRNA must be delivered to the cytosol of target cells. One of the leading...
Arctic-boreal regions are exhibiting the symptoms of profound ecological shifts as they experience pronounced warming. Wildlife in high-latitudes are one such harbinger of change, and their populations are undergoing range-shifts, declines, and extinctions in response to their rapidly altering habitats. As the circumpolar and boreal north is snow-covered for up...
The primary focus of this work is on examining structure-property relationships of interest for high-power nonlinear optical and laser crystals. An intuitive and simply illustrated method for assessing the nonlinear optical potential of structurally characterized noncentrosymmetric materials is introduced. This method is applied to materials including common quartz and tourmaline...
New transparent p- and n-type semiconductors and luminescent materials have been prepared and characterized. Synthesis, structures, optical and electrical properties of new chalcogenide fluoride p-type transparent semiconductors MCuQF (M=Ba, Sr; Q=S, Se, Te) are described. Band-gap tuning and improvement in conductivity through p-type doping are demonstrated in the family. The...
A survey of the major bodies of water, temporary and perennial,
in the region of Northern Utah revealed a limited distribution of
the Notostraca. Lepidurus (Linn.), the only representative
found, was restricted to a single temporary shallow lake. Dry Lake,
in the southern end of Cache County.
Dry Lake occupies...