This thesis describes the development of a new enantioselective synthetic method employing chiral cis-2,5-diaminobicyclo[2.2.2]octane-based organometallic catalysts. The significance of this new method to organic synthesis is illustrated with preparation of enantioenriched products that are transformed to important pharmaceutical agents. Chapter 1 provides a brief historical overview of asymmetric catalysis, especially...
Early seral forests regenerating from stand-replacing disturbances provide unique habitat for many species in productive, temperate forest landscapes and contribute to supporting biodiversity. Population declines in some species associated with early seral forests have prompted concerns about the conservation of these habitats, particularly the characteristic structural and compositional complexity associated...
The use of Native American fire regimes evolved in the Klamath-Siskiyou bioregion over millennia. A mixture of Native American and Euro-American socio-cultural management has developed from adaptations to climate, topography, ecological processes, and land use practices. This research incorporates Traditional Ecological Knowledge (TEK) to partially examine the role of tribal...