Lycopodium alkaloids have generated enormous amounts of interest from the scientific community, both as synthetic targets and for their medicinal properties. Herein is described work towards a unifying approach to large segments of the Lycopodium family. An organocatalyzed intramolecular heteroatom Michael reaction method, for the construction of piperidine and piperizine...
Releasing hatchery reared salmon and steelhead to supplement threatened and endangered populations is a widely used conservation tool. One issue with this strategy is hatchery fish have lower reproductive fitness than wild fish when spawning in the wild. One of the drivers of fitness loss in steelhead is adaptation to...
Carboxylic acids have played an important role in the field of actinide (An) and lanthanide (Ln) separations and the reprocessing of irradiated nuclear fuel. Recent bench-scale experiments have demonstrated that 3-carboxy-3-hydroxypentanedioic acid (citric acid) is a promising aqueous complexant that can effectively aid in the separation of transition metals from...
Present GEK (Geomagnetic Electrokinetograph) theory is extended
to include internal waves of the lowest mode. The predicted
towed electrode GEK signal is determined to second-order for long-crested
internal waves in a finite but deep ocean. The analysis includes
the determination of GEK signatures for small amplitude and
finite amplitude interfacial...
Global increases in ultraviolet-B radiation (UVBR:290-
320 nm) resulting from decreases in stratospheric ozone
concentration have the potential to alter marine primary
production and affect global climate and marine trophic
dynamics. Effects of UVBR on phytoplankton carbon fixation
were determined from open ocean exposure studies conducted
off the coast of...
Contamination events at Oak Creek, which runs through Oregon State University Research lands, prompted investigations into alternate transport mechanisms for moving liquid effluent from OSU Diary lands to Oak Creek. Magnetometer surveys conducted at the Diary identified magnetic signatures spatially associated with sub-surface locations of drain tiles, a 12-inch pipe,...
Experimental data on the structural phase changes in zirconia are summarized. The computational techniques of molecular dynamics are reviewed and equations of motion are formulated which allow the study of phase changes as a function of temperature and pressure. The molecular dynamics program NPT which was written for this purpose...
New syntheses for 2-bicyclo(3.3.1)nonanone and 7-bicyclo-(3.3.1)nonen-2-one were developed. The saturated ketone was prepared
from phenol and acrylonitrile via a novel intramolecular
S[subscript N]2 cyclization process. A Friedel-Crafts cyclization of 3-(3-cyclohexenyl)propanoyl chloride permitted synthesis of the unsaturated
ketone from 4-cyclohexene carboxaldehyde. The formation of
the bicyclo(3.3.1)nonane rather than a bicyclo(3.2.2)nonane skeleton...
Replication associated protein and enzyme activity levels increase as cells enter
S-phase of the cell cycle and diminish as cells leave S-phase. Accordingly, replication
associated functions decrease as myoblasts withdraw from the cell cycle to terminally
differentiate. In an effort to understand signals effecting growth associated expression
of genes, the...
We monitored larval Lost River and shortnose suckers from natal beds in the Williamson and Sprague rivers to nursery grounds in Upper Klamath Lake. Downstream movements occurred at night, in the middle of the channel, and on the falling limb of the hydrograph. Ages, sizes, and developmental stages of larvae...
How complex traits evolve continues to be a major focus of evolutionary
investigation. A current topic of debate is the hypothesis that the phenotypic
integration of complex traits gives rise to evolutionary constraints. I studied two color
traits in the common garter snake, Thamnophis sirtalis, that show a high level...
Marine sediments are one of the largest habitats for microbial life on earth. These microorganisms play critical roles in biogeochemical cycling both within the subsurface and between the sediment and water columns. However, microbial communities in sediments are highly heterogeneous and the factors defining microbial community structure and metabolic function...