The thermal and anionic rearrangements of substituted 1-vinyltrans-
cyclotridec-3-en-l-ol compounds have been studied to determine
what effects substituents would have on the sigmatropic shift when
placed on the two positions of the 1-vinyl group.
For the thermal rearrangements, the a-substituted vinyl-trans-cyclotridecenols
gave both the [3,3] and [1,3] shift products of...
E8,E10-dodecadien-1-ol, the primary component of the female sex pheromone of codling moth, Cydia pomonella L., has no attraction to male Oriental fruit moth (OFM), C. molesta (Busck). However, this compound when added to the OFM pheromone blend of Z8-dodecenyl acetate (85.5%), E8-dodecenyl acetate (5.5%), and Z8- dodecen -1 -ol (9.0%),...
Green bean flavor has been studied since the 1960’s to better understand Blue Lake flavor in processed green beans in Oregon. Research by Stevens and colleagues showed that Blue Lake flavor could be reconstituted in a bland bean by adding 0.4ppm of 1-octen-3-ol and 1.6ppm of 3-hexen-1-ol. These two volatile...
The retro-ene reaction of 2-vinylcyclohexanols occurs readily
in the vapor phase at 400-450° producing unsaturated carbonyl
compounds in good yields. The starting- materials were prepared in
general by the carbenoid addition reaction of ethyl diazoacetate,
appropriately substituted cyclohexene, and copper catalyst to
produce bicyclic esters which were reduced to the...
The potassium salts of a series of 1-vinylcycloalk-3-en-l-ols were found to undergo ring expanding [1, 3]-sigmatropic shifts at 25° when dissolved in hexamethylphosphoramide (HMPA) or 1, 2-dimethoxyethane (DME) with 18-crown-6. The yields and reaction rates were compared with those of the corresponding Siloxy-Cope ring expansions. These anionic cases showed about...
Oxidative stress occurs when the balance between reactive oxygen species and antioxidant defense mechanisms in the body becomes tipped heavily in favor of the reactive oxygen species. Reactive oxygen species can be present in excess due to elevated O2 levels, radiation, infection, smoking, or even excessive exercise. It is also...
New syntheses for 2-bicyclo(3.3.1)nonanone and 7-bicyclo-(3.3.1)nonen-2-one were developed. The saturated ketone was prepared
from phenol and acrylonitrile via a novel intramolecular
S[subscript N]2 cyclization process. A Friedel-Crafts cyclization of 3-(3-cyclohexenyl)propanoyl chloride permitted synthesis of the unsaturated
ketone from 4-cyclohexene carboxaldehyde. The formation of
the bicyclo(3.3.1)nonane rather than a bicyclo(3.2.2)nonane skeleton...
The issue of global climate change and an increasing interest in the reduction of fossil fuel carbon dioxide emissions by using forest biomass for energy production has increased the importance of quantifying forest biomass in recent years. The official U.S. forest carbon reporting is based on the forest biomass estimates...
An econometric model of the canned tuna market is used to evaluate biased and unbiased estimators. Four methods for improving mean square error when multicollinearity is present in a regression equation are examined and compared with the results of ordinary least squares (OLS). Exact and inexact prior information methods are...