Boiling dynamics and related heat transfer mechanisms have been widely studied for several decades. During that time, incredible progress has been made on quantifying bubble departure phenomena including growth rate, departure frequency, associated natural and forced convection, and radiation additions to the overall heat transfer rate. With this, the thermal...
Small pelagic fish represent a critical trophic link between plankton and large predators in marine upwelling ecosystems such as the California Current System. Populations of these fish are highly variable over time and are characterized by extreme fluctuations in abundance, which have significant ecosystem impacts. The causes driving
this instability...
Laser Powder Bed Fusion (LPBF) is a process commonly used to create additively manufactured metal parts. The flexibility and complexity allowed by the LPBF process provides opportunity for significant advancement in multiple industries as parts can be customized in shape and function for specific needs. These benefits can be compounded...
Plant viruses have been instrumental in our understanding of the biophysical properties pertaining to non-enveloped icosahedral virus particles. A substantial amount of research has been performed over five decades on Turnip yellow mosaic virus (TYMV), arguably one of the most extensively studied icosahedral plant viruses and the type-member of the...
This dissertation focuses on defining underlying mechanisms to enable the bio-inspired design of aerodynamic and/or hydrodynamic vehicles that operate within complex environments. This dissertation introduces four overarching research gaps found in current bio-inspired design research and four corresponding approach questions that guide the framework of the presented research. This research...
Due to the high cost of precursor materials, complex oxides of 4d and 5d transition metals are under-studied compared to their 3d counterparts. Recent studies have shown that oxides containing heavier transition metals can exhibit exotic electronic states due to presence of strong spin-orbit coupling. The goal of this dissertation...
Forests face health threats from pests and diseases (e.g., mountain pine beetle, emerald ash borer, chestnut blight [CB], Swiss needle cast), and other issues such as climate change. Interventions such as genetic engineering (GE) have shown promise for mitigating some of these threats. CB, for example, has impacted most American...
The phantom midges (Diptera: Chaoboridae) are a relatively small fly family composed of 50 extant species in six genera. Larvae are of interest to limnologists and ecologists because of their tolerance to toxicants, predatory avoidance strategies, and the role chaoborids play in zooplankton community dynamics. Relative to mosquitoes, systematists have...
This thesis involves analyses of 3₂-helices, a-helices and of the change in residual
entropy of a protein upon chemical modification. Part of the long-term goal of
understanding the formation, function and stability of proteins requires that all
conformations be accurately assigned and structurally understood. By a statistical
analysis of 258...
The first asymmetric synthesis of (-)-7-epicylindrospermopsin via intramolecular nitrone cycloaddition is described. The synthesis utilized a convergent approach to prepare the cycloaddition precursor 176, which was assembled by condensation of hydroxylamine 175 with aldehyde 145. Hydroxylamine 175 was synthesized from ethylene glycol (166) in seven steps. Aldehyde 145 was completed...