Advances in plant construction within the energy and chemical process industries require inexpensive process intensification (PI) technology as a means to reduce plant size for enabling modular construction. One form of PI is microchannel process technology where arrays of microchannels, having hydraulic diameters on the order of 0.1 to 1...
The primary goal of my studies was to elucidate the mechanisms for the well-recognized interaction between two nutrients, vitamins E and K. The outcomes from my studies assess mechanisms for adverse effects of vitamin E and provide novel information on mechanisms for vitamin K homeostasis. These findings will provide information...
7,7'-Dihydroxy-8,8'-biquinolyl (azaBINOL) was prepared from 7-hydroxyquinoline via N,N-dimethyl O-quinol-7-yl carbamate by directed ortho-metallation followed by FeCl₃-mediated oxidative coupling of the 8-lithioquinoline intermediate. Saponification of the resulting dicarbamate provided crystalline (±)-azaBINOL in 56% overall yield. 6,6'-Bis(dimethylaminocarbonyl)-7,7'-dihydroxy-8,8´-biquinolyl was prepared from the same dicarbamate by a double anionic-Fries rearrangement in 43% yield. 7,7'-Bis(diethylamino-carbonyloxy)-6,6'-diiodo-8,8´-biquinolyl...
The records of a population of sex-linked dwarf layers
at the Oregon State Agricultural Experiment Station subjected
to an accelerated selection for hen-housed egg production at
40 weeks of age for a period of over 11 years were analyzed
for selection response, and for the estimation of genetic
parameters. The...
Sulfoxide-ligand exchange (SLE) and asymmetric halogen-metal exchange (AHME) processes were separately examined for the enantioselective synthesis of functionalized alpha-haloalkylmetal (carbenoid) reagents. Carbenoids derived from SLE were used to effect stereospecific reagent-controlled homologation (StReCH) of boronic esters and those generated via AHME were engaged in Darzens-type chemistry with aldehydes.
Abstract for...
Reinterpretation of the leafhopper tribe Scaphytopiini reveals it
to be primarily a New World taxon with only limited representation in
the Palearctic, Oriental and possibly Ethiopian regions. Approximately
75 species assigned to three genera are known from the United
States and Canada with at least another 75 species representing an...
Manufacturing process design (MPD) represents a design-oriented approach to manufacturing engineering. In this dissertation, Haynes 230 (H230), a solid solution-strengthened Ni-based superalloy, was chosen to meet the material requirements of a microchannel solar receiver (MSR) needed to increase the efficiency and reduce the cost of solar thermal power generation. An...
Transient liquid-phase diffusion brazing is used in precision, hermetic joining applications as a replacement for diffusion bonding to reduce cycle times, reduce bonding pressure and improve yields. Studies showed that the interlayer used in diffusion brazing can be detrimental due to the use of melting point depressants (MPDs). The goal...
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Brian K. Paul
Transient liquid-phase diffusion brazing is used in precision, hermetic
High temperature microchannel heat recuperators (HTμRs) offer an efficient means of improving reactor process thermal efficiency by offering smaller form factors due to increased heat transfer surface area density and volumetric heat transfer rate over traditional heat exchanger designs. To date, HTμRs face cost and reliability challenges. In this work,...