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[Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition

Creator:: Sanguanruang, Oravan
Resource Type:: Dissertation
Full Text:: like to express my deep gratitude to Dr. James H. Krueger for his advice, patience and understanding

A study of the iodine-formate reaction in dimethylsulfoxide-water mixtures

Creator:: Hiller, Frederick Wayne
Resource Type:: Dissertation
Full Text:: , I3 + HCOO -.CO2 + 3I + H +. The rate law, rate = k[ E I2] [ HCOO ] [ I ] - 1, is observed in all

A kinetic investigation of the hydrolysis of trimethylamine-sulfur trioxide in dimethyl sulfoxide-water solvents

Creator:: Johnson, William Allen
Resource Type:: Dissertation
Full Text:: Trioxide in Dimethyl Sulfoxide -Water Solvents Redacted for privacy Abstract approved: J. Krueger The

A kinetic investigation of the mechanism and intermediates of the chromium(VI)-Iodide reaction

Creator:: Gaswick, Dennis Charles
Resource Type:: Dissertation
Full Text:: for Privacy Abstract approved: James Krueger (s) The kinetics of the reaction between HCrO4 and I in

Kinetics and mechanisms of displacement reactions involving trithionate ion

Creator:: Ritter, Ronald Dale
Resource Type:: Dissertation
Full Text:: presence of S03 2- and excess trithionate. 2- SO 3 -C6H5S + S306 C 6 H 5 SSO 3 + S203 2- The reaction

Nucleophilic substitution at nitrogen : mechanisms and intermediates involved in substitution reactions of the hydroxylamine-o-sulfonate ion

Creator:: Blanchet, Pierre François
Resource Type:: Dissertation
Full Text:: SUBSTITUTION REACTIONS OF THE HYDROXYLAMINE-0- SULFONATE Redacted for privacy Abstract approved: James H

Characterization of a trivalent-nitrogen center. Nucleophilic substitution on hydroxylamine-o-sulfonic acid in dimethyl sulfoxide-water solvents

Creator:: Sudbury, Barry Arnold
Resource Type:: Dissertation
Full Text:: Fellowship (1970- 1973). Dr. J. H. Krueger has used excellent judgement as an edu- cator and research

Reactions and stereochemistry of thiolato and sulfenato cobalt (III) complexes

Creator:: Herting, Daniel L.
Abstract:: This thesis describes a study of the synthesis, stereochemistry, and reactivity of cobalt(III) cysteinato (CyS) and related thiolato complexes. The preparation of [Co(en)₂CyS]⁺ resulted in a product solution containing a mixture of diastereomers in the ratio 2.3:1 (Δ:A). The isomers were separated by ion exchange chromatography, and their absolute configurations...
Resource Type:: Dissertation
Full Text:: . Herting ACKNOWLEDGEMENTS Most of my thanks go to Dr. James H. Krueger. He was always willing to share

Synthesis and oxidation of cysteine- and penicillamine- containing Fe(III) and Co(III) complexes. Analogs for the active metal sites of the cysteine and cysteamine dioxygenases

Creator:: Miller, Krys J.
Abstract:: The first part of this thesis describes a study of the characteristics of oxidation of a 1:2 iron(III):thiolate system in methanolic solution and in water. This system was investigated as a potential analog for the cysteine- and cysteamine-dioxygenase catalyzed 0₂-oxidation of cysteine and cysteamine, respectively, to the corresponding sulfinic acids....
Resource Type:: Dissertation
Full Text:: . Abstract approved: Redacted for Privacy Dr. Yamei H. Krueger C) The first part of this thesis describes a

Synthesis and oxidation of metal-thiolate compounds which mimic the active site function of thiolate dioxygenase enzymes

Creator:: Schussel, Leonard J.
Abstract:: Part I describes the synthesis of bis(fac-S)((tris)2-aminoethanethiolatoiron( III))iron(III) chloride. The compound was first discovered during an attempt to prepare a ternary complex of iron, thiolate and pi-acid ligand. The compound is a reasonably air-stable iron(III)-thiolate that contains a linear tri-iron cluster with each iron bridged to the adjacent iron by...
Resource Type:: Dissertation
Full Text:: DIOXYGENASE ENZYMES Abstract approved: Redacted for Privacy Dr. James H. Krueger Part I describes the

ScholarsArchive@OSU

[Lambda hyperon]-((R)-cysteinesulfenamido-N,S) bis (ethylenediamine) cobalt(III) complex : Characterization of the complex and kinetics and mechanism of formation and base-catalyzed decomposition

A study of the iodine-formate reaction in dimethylsulfoxide-water mixtures

A kinetic investigation of the hydrolysis of trimethylamine-sulfur trioxide in dimethyl sulfoxide-water solvents

A kinetic investigation of the mechanism and intermediates of the chromium(VI)-Iodide reaction

Kinetics and mechanisms of displacement reactions involving trithionate ion

Nucleophilic substitution at nitrogen : mechanisms and intermediates involved in substitution reactions of the hydroxylamine-o-sulfonate ion

Characterization of a trivalent-nitrogen center. Nucleophilic substitution on hydroxylamine-o-sulfonic acid in dimethyl sulfoxide-water solvents

Reactions and stereochemistry of thiolato and sulfenato cobalt (III) complexes

Synthesis and oxidation of cysteine- and penicillamine- containing Fe(III) and Co(III) complexes. Analogs for the active metal sites of the cysteine and cysteamine dioxygenases

Synthesis and oxidation of metal-thiolate compounds which mimic the active site function of thiolate dioxygenase enzymes

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