The photolysis of the aqueous thymine system has been investigated
at 214 nm, 229 nm and 254 nm at room temperature. Products
of photolysis have been identified as hydrogen peroxide, 6-hydroxy-5-
hydroperoxy thymine and tentatively 5-hydroxy-6-hydroperoxy thymine.
These together with thymine loss, were determined quantitatively
under a variety of conditions....
The photochemistry of some analogs of insect growth regulators
(IGR's) was studied. Methyl geranate, TY, was synthesized and the
mechanisms of its photochemical reaction pathways were studied by a
variety of techniques. Direct irradiation of 71 in ether leads to the
formation of five new products: 98, the product of...
The photodebromination of selected bromoarenes has been studied at 300 nm
to determine the the possible mechanistic pathways leading to product.
Irradiation of 4-bromobiphenyl (BpBr) at this wavelength leads to the product
biphenyl. The quantum yield of intersystem crossing (0.98) and quenching
studies with cis-1 ,3-pentadiene suggest that the reaction...
In this dissertation, I present electronic spectroscopy of a few biologically relevant species and their complexes with solvent molecules in the gas phase using a variety of techniques, including resonantly enhanced multiphoton ionization (REMPI), laser induced fluorescence (LIF), and zero kinetic energy (ZEKE) photoelectron spectroscopy. My work on several methylated...
Irradiation of a tryptamine linked through its side-chain nitrogen to an alkylidene malonate residue results in an intramolecular [2 + 2] cycloaddition to the indole 2,3-double bond. The resultant cyclobutane undergoes spontaneous retro-Mannich fission to produce a spiro[indoline-3,3-pyrrolenine] with relative configuration defined by the orientation of substituents in the transient...
Significant inputs of hydrocarbons are continually released into the environment from anthropogenic and natural sources. Some of the most toxic hydrocarbon compounds are polycyclic aromatic hydrocarbons. Polycyclic aromatic hydrocarbons are known for their ability to absorb ultraviolet light and enhance toxicity. Generally, PAHs exert their toxicity via narcosis but UV-absorbing...
