By inverting EarthScope long-period magnetotelluric (MT) data from the southeastern United States (SEUS), we obtain electrical conductivity images that provides key insights into the geodynamics of this region. Significantly, we resolve a highly electrically resistive block that extends to mantle depths beneath the modern Piedmont and Coastal Plain physiographic provinces....
The fragmentation characteristics of protonated peptides have been investigated using
tandem mass spectrometry (MS/MS) under various fragmentation regimes and detailed
density functional theory (DFT) reaction pathway calculations. The DFT calculations
predict novel salt-bridge stabilized transition structures as well as consecutive reactions
occurring in proton-bound dimers for some of the ions...
Studies were carried out to determine the absolute stereochemistry of
botryococcene (1). The natural product was degraded to two sets of 'y- and 8-
valerolactones. All enantiomeric variations of these lactones were synthesized in
optically pure form starting from (S)- and (R)-methyloxiranes. 1H NMR correlation of
natural and synthetic materials...
The South Pole ice core (SPC14), drilled in the field seasons of 2014/2015 and 2015/2016, is an intermediate length, 1,751-m ice core which preserves a 54,000-year record of past climate and atmospheric composition. The SPC14 ice core adds to the spatial grid of ice cores in Antarctica extending into the...
Marine sediments are vast sources and reservoirs of methane, a potent greenhouse gas. Most of this methane is anaerobically oxidized by archaea before it can reach the overlying ocean, though the efficiency of this process often depends on methane fluxes and mechanisms of fluid transport. Anaerobic methanotrophic archaea, or ANME,...