Index Catalog // ScholarsArchive@OSU

Experimental investigation of supercritical heat transfer of carbon dioxide in parallel square microchannels with a single-wall constant heat flux boundary condition

Creator:: Zada, Kyle R.
Abstract:: In the vicinity of the pseudocritical point, supercritical carbon dioxide (sCO₂) undergoes a steep change in properties from “liquid-like” to “gas-like” as it is heated at a constant pressure. At the same time, there is a large spike in specific heat which can yield high heat transfer coefficients and heat...
Resource Type:: Masters Thesis

Density Functional Theory Investigation of CH Coupling and CH Hydrogenation Reactions on Different Cobalt Surface Facets and Fischer-Tropsch Temperature Swing Reactor Optimization

Creator:: Petersen, Dennis F.
Abstract:: Fischer-Tropsh Synthesis is a chemical process that converts CO and H₂ (syngas) into long stable hydrocarbon chains to use as fuel. This process suffers from large product distribution that requires expensive post processing. In this study, the reaction mechanism of hydrocarbon chain growth on Co is investigated on different surface...
Resource Type:: Masters Thesis

Force Prediction in the Compression Sealing of an Ultra-thin Elastoviscoplastic Membrane

Creator:: McNeff, Patrick Scot
Abstract:: The objective of this paper is to demonstrate a method for mechanically characterizing a 25 μm thick elastoviscoplastic hemodialysis membrane and for quantifying the force required to use that membrane in compression sealing. First, methods are developed for mechanically characterizing the thin elastoviscoplastic membrane. Then, a finite element model is...
Resource Type:: Masters Thesis

Degradation of N-Nitrosodimethylamine Using Photo-Catalysis and Microreactor Technology : Experimentation and Modeling

Creator:: Omar, Mohamed
Abstract:: The cleanliness of water is a major issue with regards to humanity's continued survival. The chlorination and chloro-amination of water is essential to the creation of microbiologically clean water. However these processes also give rise to oxidative byproducts such as nitrosamines. In particular, due to its high toxicity, N-Nitrosodimethylamine (NDMA)...
Resource Type:: Masters Thesis

Experimental Characterization of a Supercritical Carbon Dioxide Microchannel Solar Thermal Receiver

Creator:: L'Estrange, Thomas
Abstract:: Characterization of a microchannel solar thermal receiver for supercritical carbon dioxide (sCO₂) is presented. The receiver design is based on conjugate computational fluid dynamics and heat transfer simulations as well as thermo-mechanical stress analysis. Two lab scale receivers with a 2x2 cm² absorber area are fabricated and experimentally characterized -...
Resource Type:: Masters Thesis

Finite volume method modeling of corona discharge microreactor oxidization of dibenzothiophene

Creator:: Fan, Xiangru
Abstract:: The growing need for cleaner fuels requires the development of better deep fuel desulfurization methods. The current study presents a reaction model for the mechanism of dibenzothiophene oxidization by dissolved oxygen occurring in a corona discharge microreactor. In the present work, a Finite Volume Method model of the reactor is...
Resource Type:: Masters Thesis

CO2 reduction in aqueous-ionic liquid solution in microscale-based corona reactor, CO₂ reduction in aqueous-ionic liquid solution in microscale-based corona reactor

Creator:: Miao, Yu
Abstract:: Global warming problem is becoming an increasingly important environmental concern and CO₂ is considered as the major cause of global warming. Among various methods of CO₂ utilization, conversion of CO₂ to value added chemical products is the most attractive. In this study, a microscale-based corona reactor is introduced for reduction...
Resource Type:: Masters Thesis

Photochemical reduction of carbon dioxide in aqueous and ionic liquid solutions in a microreactor with TiO₂ catalyst; experiment and modeling

Creator:: Campbell, Travis J.
Abstract:: Microtechnology was used to study the chemical reduction of dissolved carbon dioxide into useful products. A novel TiO₂ photocatalyst was used to activate the reaction under ultraviolet irradiation. CO₂ was dissolved in aqueous and 50% BMIM-BF₄ (ionic liquid) solutions. The introduction of an ionic liquid increased the solubility of CO₂...
Resource Type:: Masters Thesis

Fabrication of precipitation-hardened aluminum microchannel cooling plates for adsorption-based hydrogen storage systems

Creator:: Pawar, Supriya V.
Abstract:: The need for clean and renewable fuel such as hydrogen is driven by a growing worldwide population and increasing air pollution from fossil fuels. One of the major barriers for the use of hydrogen in automotive industry is the storage of hydrogen. Physisorption is the most promising storage technique due...
Resource Type:: Masters Thesis

Intermetallic microlamination for high-temperature microreactors

Creator:: Dewey, Tyler
Abstract:: Chemical microreactors offer opportunities for portable power generation, on-site waste remediation and point-of-use chemical synthesis. Much of the existing development of microreactor devices involves silicon-based microfabrication techniques. It is recognized that new refractory materials are important to realizing high-temperature microreactors. Requirements of these materials include high-temperature resistance, chemical inertness and...
Resource Type:: Masters Thesis

ScholarsArchive@OSU

Experimental investigation of supercritical heat transfer of carbon dioxide in parallel square microchannels with a single-wall constant heat flux boundary condition

Density Functional Theory Investigation of CH Coupling and CH Hydrogenation Reactions on Different Cobalt Surface Facets and Fischer-Tropsch Temperature Swing Reactor Optimization

Force Prediction in the Compression Sealing of an Ultra-thin Elastoviscoplastic Membrane

Degradation of N-Nitrosodimethylamine Using Photo-Catalysis and Microreactor Technology : Experimentation and Modeling

Experimental Characterization of a Supercritical Carbon Dioxide Microchannel Solar Thermal Receiver

Finite volume method modeling of corona discharge microreactor oxidization of dibenzothiophene

CO2 reduction in aqueous-ionic liquid solution in microscale-based corona reactor, CO₂ reduction in aqueous-ionic liquid solution in microscale-based corona reactor

Photochemical reduction of carbon dioxide in aqueous and ionic liquid solutions in a microreactor with TiO₂ catalyst; experiment and modeling

Fabrication of precipitation-hardened aluminum microchannel cooling plates for adsorption-based hydrogen storage systems

Intermetallic microlamination for high-temperature microreactors

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