In this thesis, I present a new method we developed to study low frequency (< 700 cm⁻¹) vibrational dynamics: Time-resolved third-harmonic generation (TRTHG) spectroscopy. Among a variety of vibrational spectroscopy techniques, TRTHG differentiates itself with robustness, versatility, and simplicity. In TRTHG experiment, that involves only two ultrashort laser pulses, the...
Nature is an inspirational source of silica structures that possess unique optical properties. A few classes of organisms fabricate metal oxides with nanoscale features by a bottom-up self assembly process. In particular, diatoms are a prolific class of single-celled algae that possess silica shells or “frustules” with intricate submicron scale...
Regiochemistry of intramolecular [2+2] photocycloadditions of oxygenated
6-alkenyl-3-alkoxy-2-cyclohexenones is studied. Application of this methodology
to construct a key intermediate [3.3.2] bicyclic skeleton of ryanodol is described
as well. Irradiation of (3-butenyl)compounds 3, 11, 14 and of (4-pentenyl)compound 6 afforded exclusively the linear photoadducts 4, 12, 15 and
7 respectively. Irradiation...
Identifying the most relevant items in an e-commerce site is becoming more and more
difficult nowadays because of the heavy overload of information. A Java Recommender
System that uses Collaborative Filtering techniques has been developed to reduce such
information overload and even personalize the information to the individual’s preference.
The...
With growing concerns on environment impact of industrial product development, the product developers are seeking better solutions to achieve desired environmental benign requirements by the regulators and customers besides economic growth. During the last decade, some of the most successful product development companies (such as HP) have established their own...
Numerical simulation of the January and July global
climate with the OSU two-level atmospheric general circulation
model has generated time series of the global
distribution of selected climatic variables. Analyses of
these data for the kinetic energy and available potential
energy based on 31-day time mean statistics have been
made...
Circuits operating outside the earth’s atmosphere are more vulnerable to cosmic radiation and require special design consideration. The purpose of this work is to explore methods of mitigating the effect of radiation in phase locked loop (PLL) circuits. Several voltage controlled oscillators (VCOs) and two complete PLLs are designed and...
In the year 2007, the worldwide energy consumption accumulated to a total of 16.5 billion MWh. While the resources of conventional energy production cause environmental damage, renewable energy sources like solar or wind power offer a solution to substitute for coal or nuclear generated power. Countries like Denmark and Spain...
As metropolitan governments explore density-promoting “smart growth” policies, finer analysis is needed to quantify the impact of such changes on households’ transportation and housing costs. Existing research suggests that households in urban areas face a trade-off between living in areas with higher housing costs and lower transportation costs or the...