The corrosion and degradation of Ni and its alloys in supercritical carbon dioxide (Sc-CO2) is an emerging issue for material selection and implementation of Sc-CO2 thermal cycles in industry. In this study, we apply density functional theory (DFT) to study the initial steps of carburization of the Ni (111) surface...
Fischer-Tropsh Synthesis is a chemical process that converts CO and H₂ (syngas) into long stable hydrocarbon chains to use as fuel. This process suffers from large product distribution that requires expensive post processing. In this study, the reaction mechanism of hydrocarbon chain growth on Co is investigated on different surface...
Dry reforming of methane to syngas using CO2 was performed in a solar-driven milli-scale reactor, which converts solar energy to chemical energy. The process aims to upgrade the energy content of the feed stream using sustainable energy. The effect of mean residence time, temperature and CO2:CH4 ratio on conversion and...
Microtechnology was used to study the chemical reduction of dissolved carbon dioxide into useful products. A novel TiO₂ photocatalyst was used to activate the reaction under ultraviolet irradiation. CO₂ was dissolved in aqueous and 50% BMIM-BF₄ (ionic liquid) solutions. The introduction of an ionic liquid increased the solubility of CO₂...
Pesticides benefit agriculture by increasing crop yield, quality, and security. However, pesticides may inadvertently harm bees, which are valuable as pollinators. Thus, candidate pesticides in development pipelines must be assessed for toxicity to bees.
Leveraging a data set of 382 molecules with toxicity labels from honey bee exposure experiments, we...
Global warming problem is becoming an increasingly important environmental concern and CO₂ is considered as the major cause of global warming. Among various methods of CO₂ utilization, conversion of CO₂ to value added chemical products is the most attractive. In this study, a microscale-based corona reactor is introduced for reduction...
Photoluminescence (PL) materials have attracted a lot of attention in last several decades. Recently PL materials, which can convert low-efficiency Ultraviolet (UV) or Infrared (IR) light to high-efficiency visible light, have been widely applied in the research of improving conversion efficiency of solar cell. As one of the most common...
High energy density ceramic capacitors with temperature stable permittivity across -150°C to 300°C are desired for a wide variety of electronic devices. Traditional dielectrics such as barium titanate provide a high permittivity but that permittivity is strongly temperature dependent over this specified temperature range. The goal of this work is...
The objective of this study is to investigate the dispersion of solute matter introduced into a fully developed laminar flow in a circular capillary tube under preasymptotic regimes. For this purpose, we have used the method of volume averaging to upscale microscale balance equations for the case of diffusion-convection transport...
The rapid accumulation of plastic waste in landfill, waterways and oceans is becoming a critical problem, one that current recycling technologies are not capable of solving. Recent proposed approaches in the depolymerization of waste plastics employ an Olefin-Intermediate Process (OIP), where feedstocks like polyolefin plastics are ‘activated,’ producing an olefin...
In the face of a disruptive event or prolonged period of stress, resilient performance ischaracterized by preventative measures, effective response, and the integration of lessonslearned. In healthcare, resilience significantly affects patient safety. However, currentguidelines for healthcare performance assessment, such as the Triple Aim, do notconsider physician satisfaction and preventative measures...
Hafnium Oxide thin films has had growing attention due hafnium oxide being used as a gate dielectric for MOSFET transistors and a potential next generation photoresist for sub 20 nm patterns. Extreme Ultra-Violet (EUV) lithography has been identified as the primary candidate technology for generation of sub-20 nm patterns. Current...
This thesis presents an experimental study of radial porosity in a manually filled cylindrical container with glass spheres. The symmetric distribution of bead diameter allowed for normalization of container properties and porosity models. The aspect ratio of the container was approximately 3.9, with tube-to-particle-diameter ratio λ ≈ 24.6 and height-to-particle-diameter...
In recent years, model-free Deep Reinforcement Learning (RL) has become an increasingly popular alternative to more traditional model-based or optimization-based control methods in solving robotic legged locomotion. However, deploying RL in the real world can be a significant undertaking. Constructing reward functions which compel controllers to learn the desired behavior...
Copper zinc tin sulfide (CZTS) is a potential solar material for thin film solar cells according to its suitable band gap in the visible light range, high absorption coefficient, low toxicity, good photostability and relative earth abundance of component elements. However, the production cost of this solar thin film material...
Burnout is a state of physical or emotional exhaustion and disconnectedness induced by continuous stress that affects various aspects of an individual’s life. Physicians experience burnout at a higher rate than other professions due to the highly stressful nature of their work. Consequently, physicians are at a higher risk of...
To address several challenges faced in healthcare, the Triple Aim (3A) was targeted by institutions to improve health outcomes and patient experience while reducing the costs of health. Process improvement techniques in manufacturing, such as Lean systems, were applied as tools to achieve the 3A framework. Unfortunately, the high level...
The need for less toxic quantum dots (QDs) has led to a significant number of investigations related to copper indium sulfide (CIS) QDs. Lower toxicity and broad band absorbance width makes CIS QDs appealing for light emitting diodes (LEDs), lasers, sensors, bio-imaging, solar cells, and computing. The optical and electronic...
Boiling heat transfer is studied for its ability to dissipate high fluxes and achieve heat transfer coefficients two orders of magnitude greater than single-phase heat transfer systems. Heater surface enhancement with increased surface area, varied geometry, wettability contrast and micro/nano-structures can further enhance boiling heat transfer performance through bubble nucleation...
Many projects fail because employees and managers have different understandings of project "success" or "value". Other projects fail because managers are unable to effectively align organizational values with those of their employees. This problem is widely understood, but there is little empirical research that specifies the nature and effect of...
Population growth driven sustainability issues, including the food resource issue, are pressing problems in need of attention. The goal of the present thesis is to examine the ability of an electric non-thermal plasma based microreactor to destroy ethylene, a known plant hormone responsible for losses in the range of 20%...
Steam distillation has been the common method of extraction of essential oils from plants for more than a century. The use of microwave energy has been suggested as an alternative distillation method that would: reduce water usage, dependence on non-renewable energy sources, and the carbon footprint. A byproduct of this...
Nanoparticles have become more prevalent from their use in sunscreen to antimicrobial agents in socks. In light of these applications, gaining a fundamental understanding of how NPs interact with humans is crucial for their future. Specifically, how cells interact with NPs and what factors drive the modes of cellular uptake....
Recent studies have indicated that nickel gallium alloys can be effective for the catalytic hydrogenation of CO2 to methanol. To simplify the characterization of NiGa catalysts, we are developing model systems using NiGa thin films. We prepared NiGa thin films by RF magnetron sputtering using an equiatomic alloy target, followed...
Cobalt germanides have been widely studied as semiconductor contact materials, but recent theoretical studies suggest that they may also be excellent catalysts for methane steam reforming with stabilities and activities comparable to noble metal catalysts. In order to study the catalytic activity of cobalt germanides, it is critical to first...
A study of the effect of catalyst properties on the synthesis of carbon nanotubes (CNTs) is done in this thesis. Three different metal alloy catalysts, Fe/Ti, Ni/Ti, Co/Ti, have been studied. Various atomic concentrations and thicknesses were cosputter deposited on clean Si wafers using AJA Orion 4 RF Magnetron sputter...
We present student perceptions of a new first-year engineering programming class that was designed by informed research practices. While the College of Engineering at Oregon State University saw a lot of major switching in the first year, there were not many students switching into computer science (CS). This could have...
Naked (hull-less) barley has historically been grown for food, but interest in, and breeding efforts for, its use in malting and brewing have increased due to the potential benefits: reduced off-flavors, reduced spent grain, and higher malt extract. These benefits are offset by limiting factors such as high b-glucan and...
Flexible electronics processing techniques were applied to integrate a glucose sensor with a hormone-delivery catheter in order to create a cheap and minimally invasive method for patients with type 1 diabetes to continually monitor and control their blood sugar levels. Ultimately, this work intends to move toward the development of...