Environmental factors such as temperature, air, and water can have a profound
effect on the durability of asphalt concrete mixtures. In mild climates where good
quality aggregates and asphalt cement are available, the major contribution to
deterioration may be due to traffic loading and the resultant distress is manifested
in...
Phytophthora cinnamomi is a soilborne pathogen that causes root rot disease of highbush blueberry (Vaccinium corymbosum L.). When new installations of susceptible blueberry cultivars are infected with P. cinnamomi, plants often fail to grow significant new tissue, greatly reducing yields over the life of the planting. Chemical fungicides are available...
β-chitin/chitosan extracted from newly utilized jumbo squid (Dosidicus gigas) pens were investigated in respect to their physicochemical properties, polymeric structures, deacetylation and depolymerization characteristics, and antioxidant and antibacterial activities. These functional properties were further compared with α-chitin/chitosan prepared from shrimp shells. Due to the low mineral content (< 1%) and...
Grid-scale energy storage systems are urgently needed to increase the flexibility and rigidity of the grid for modern society and take full advantage of the renewable green energy resources such as solar energy and wind energy. Na-ion batteries (NIBs) and K-ion batteries (KIBs) have been emerged as one of the...
This dissertation is informally divided into three major sections. In the first section (Chapter 2) I use data from field mapping, isotopic geochronology, whole rock geochemistry and trace element concentrations in zircons to examine the petrology, geochemistry and ages of the Haquira East porphyry copper deposit of southern Peru. In...
Biotic and abiotic processes at continent-ocean interfaces cycle a disproportionate mass of carbon and nutrients relative to their global surface area, and microbial activity is a principal determinant of organic and inorganic matter flux in these transition zones. Most studies using modern high-throughput ‘omics techniques to link microorganisms with costal...
Recent blackout events consistently show that a variety of mechanisms are involved in cascading outages. These cascading mechanisms are irregularly modeled and validated within the existing literature and industry practices. Understanding the relative significance of these different mechanisms is important for choosing which one(s) needs to be modeled for specific...
Piezoelectric materials have been widely used in electromechanical actuators, sensors, and ultrasonic transducers. Among these materials, lead zirconate titanate Pb(Zr[subscript 1‐x]Ti[subscript x])O₃ (PZT) has been primarily investigated due to its excellent piezoelectric properties. However, environmental concerns due to the toxicity of PbO have led to investigations into alternative materials systems....
Piezoelectric materials convert mechanical strain into a dielectric displacement, as well as the converse, allowing these materials to be used as sensors, actuators, and transducers. Currently, lead zirconate titanate (PZT) is the primary material used in these applications. Due to environmental toxicity and safety concerns associated with Pb, development of...
The ubiquity of high quality video and proliferation of mobile devices has contributed to an unprecedented rise in video consumption. HTTP, in conjunction with adaptive streaming, has become the de facto mechanism for delivering the vast majority of video as it readily caters to heterogeneous networks and devices. This dissertation...
The enzymes of dNTP synthesis in T4 infection associate to form a multienzyme complex, the T4 dNTP synthetase complex, facilitating the flow of metabolites en route to dNTPs, and their subsequent flow into DNA. Study of protein-protein interactions helps one to understand how the enzymes in the complex are organized...
Conventional soil maps represent a valuable source of information about soil
characteristics, however they are subjective, very expensive, and time-consuming to
prepare. Also, they do not include explicit information about the conceptual mental
model used in developing them nor information about their accuracy, in addition to the
error associated with...
The critically endangered Maui's dolphin (Cephalorhynchus hectori maui) and the endangered Hector's dolphin (C. h. hectori) are endemic to the coastal waters of New Zealand, where their primary threat is fisheries-related mortality. The Maui's dolphin is among the most critically endangered cetaceans in the world, with its remnant population primarily...
Much recent research has focused on the development lead-free perovskite piezoelectrics as environmentally compatible alternatives to lead zirconate titanate (PZT). Two main categories of lead free perovskite piezoelectric ceramic systems were investigated as potential replacements to lead zirconate titanate (PZT) for actuator devices. First, solid solutions based on Li, Ta,...
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Fig. 2.8 Post-fatigue hysteresis (2x107 cycles at 2Ec) with Eapp decreasing from 4 to 2 Ec
The effects of ultraviolet (UV) irradiation on photosynthesis and
various partial reactions involving the individual photoreactions of
photosynthesis were examined. These reactions included photo-reduction in adapted green algae, Hill reaction, cyclic photophosphorylation,
the 520 nm absorbance change and variable-yield fluorescence.
The reactions were measured in spinach chloroplasts and
isolated chloroplasts...
CIGS and CdTe based commercial thin-film solar cells (TFSCs) require an absorber thickness greater than 2 µm and 4 µm, respectively, to adequately absorb the solar spectrum. To efficiently extract photoexcited electrons, these TFSCs require relatively defect-free absorbers with high-minority carrier mobility (> 100 cm2V−1s−1) and long lifetime (> 10...
Quick and accurate measurements of nanoparticles have important applications in biology, environmental and non-proliferation areas. Calculation of isotopic ratios, particularly in special nuclear materials, has relied on integration of nanoparticle counts and limited the capability of counting minor isotopes. Rapid transient detection method of nanoparticles has demonstrated the effectiveness of...
Thin films of wide band-gap semiconductors are deposited by the pulsed laser deposition method. Optimal deposition parameters for the individual compounds are reported. A family of p-type BaCuQF (Q = S, Se, Te) ceramics with a layered crystalline structure is investigated for active and passive device applications.
Epitaxial films of...
The first area of investigation involves the electron transport
of sub-mitochondrial particles and their components. The second
area is the synthesis of ATP and other energy linked reactions and
components of the energy conservation and transfer apparatus.
Investigations on the nature of the tetramethyl-p-phenylenediamine
(TMPD) shunt indicated that tetrachlorohydroquinone (TCHQ)...
Occult deposition is the direct uptake of cloudwater by vegetation that comes into
physical contact with wind-driven cloud droplets. This can be a significant pathway for
hydrological and chemical fluxes from the atmosphere to some forests. Methods for
estimating cloudwater fluxes to forests are reviewed. Previous studies have neglected
the...
This thesis details my investigation of some pharmaceuticals and natural products on the transport of drugs which are substrates of P-glycoprotein (P-gp), such as cyclosporin A (CSA) and digoxin by using Caco-2 and MDCKII-MDR1 drug transport models. Three objectives were performed to address this goal. The first objective was to...
Two light sensitive mutants of the green alga Scenedesmus obliquus strain D₃ have been characterized. The photodynamic nature of their sensitivity has been established, the subchloroplast site of photodamage has been investigated, and their noncarotenogenic character has been verified. The two mutants possess several similarities, although mutant L. S. -41...
The closed insulated pallet system (CIPS) was evaluated for growth, yield, and
fruit quality of tomato genotypes with determinate growth habit. Plants were irrigated
with several levels of sodium chloride (NaCl) salinized water. Tomato growth and yield
were significantly greater in CIPS than in conventional surface-irrigated containers,
regardless of irrigation...
Measurements are made of the conductivity and Hall mobility of
liquid solutions of thallium-tellurium, in compositions ranging from
pure tellurium to 69.0 atomic percent thallium. At compositions on
the thallium-rich side of intrinsic composition (66.7 atomic percent
thallium) both the conductivity and Hall mobility are temperature
independent, and the data...
Pseudomonas is a diverse, ubiquitous, and widely studied genus of bacteria. As Pseudomonas species occupy a wide range of niches in the ecosystem, they have made remarkable biological impacts. Better understanding of Pseudomonas biology, genetic diversity, and functional interactions with other organisms and the environment will provide valuable insights into...
Metagenomics has revealed that the marine microbial biosphere is immensely more diverse than originally considered, and is an almost untapped reservoir for the potential discovery of microbial natural products. Despite numerous advances in culturing, biosynthetic engineering and genomic-based screening efforts to uncover much of this diversity in relatively accessible environments,...
This work explores the electric field induced strain mechanisms in environmentally benign Bi0.5Na0.5TiO3 (BNT) based piezoelectric thin films. Although BNT-based materials show promise as replacements for toxic Pb-based piezoelectrics, the displacement mechanisms are not consistent between thin films and bulk materials, and the differences have yet to be well understood....
Earth’s mantle extends to nearly 3000 km depth, comprises >80 % of Earth’s total volume, and has the largest influence on the primordial and radiogenic heat budget. Despite its importance, the structure and composition of the mantle is still debated. There are three primary models for Earth’s mantle structure that...
Atmospheric carbon dioxide levels have been steadily increasing from anthropogenic energy production, development and use. Carbon cycling in the terrestrial biosphere, particularly forest ecosystems, has an important role in regulating atmospheric concentrations of carbon dioxide. US West coast forest management policies are being developed to implement forest bioenergy production while...
Muitiregion annular geometry is a basic feature of energy removal
systems ranging from advanced heat exchangers to fission reactor fuel
rods. For the symmetric cases, the heat conduction through annular regions
is well defined. However, for a shift of an annular region, analysis
of the system must be made in...
Northern highbush blueberry is a long-lived perennial crop that is well adapted to low soil pH conditions. The plants are often shallow rooted and absorb primarily the ammonium (NH₄) form of nitrogen (N) rather than nitrate-N (NO₃-N). Traditionally, commercial blueberry fields have been irrigated with overhead sprinklers and fertilized using...
Enantioenriched sp³-hybridized carbenoid reagents CR1R2MX (X = nucleofuge, M = electrofuge) of different types were investigated for the synthesis of polysubstituted alkyl chains by iterative stereospecific reagent-controlled homologation (StReCH) and for the stereospecific connective synthesis of alkenes by eliminative cross-coupling.
In the first part, putative enantioenriched α-chloroalkyllithiums (CHRLiCl) were employed...
The variegated aqueous chemistries of metal cations are applied to the design and synthesis of non-toxic solution precursors suitable for additive printing of large-area oxide electronics. Polycondensation behaviors of aqueous Al+3 and PO4 +3 are manipulated in the deposition of atomically smooth amorphous aluminum oxide phosphate (AlPO) dielectric films. AlPO...
In two studies we tested the effect of vitamin B-6
(B-6) intake on in vitro lymphocyte, proliferation and IL-2
production in healthy young women. In Study I, 6 women were
fed a constant diet containing 0.84 mg (4.96 μmols) of B-6
for 12 d, and 1.24 mg (7.33 μmols) and...
It has been well established that ferroelectric to relaxor crossover in piezoelectric ceramics exhibit promising electromechanical and dielectric properties over a wide temperature range, applying sensors and actuators transducers and such. A plethora of research has reported giant strain in various lead-free piezoelectric ceramics and attributed the reasoning to the...
The chemolithoautotrophic nitrite oxidizing bacteria (NOB) participate in the
biogeochemical cycling of nitrogen by catalyzing and conserving energy from the
oxidation of nitrite (NO₂-) to nitrate (NO₃-) via a nitrite oxidoreductase (NXR). The
main objective of this work was to comparatively annotate and analyze the genome
sequences of Nitrobacter winogradskyi...
Despite years of research, females continue to have a higher incidence of non-contact ACL injuries. One of the major findings of this research is that males and females perform certain tasks, such as, cutting, landing, and single-leg squatting, differently. In particular, females tend to move the knee into a more...