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Filtering by: Creator Gorfman, S. Remove constraint Creator: Gorfman, S. Degree Name Doctor of Philosophy (Ph.D.) Remove constraint Degree Name: Doctor of Philosophy (Ph.D.)

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  • Non-Stoichiometry in Bismuth Perovskite Solid Solutions

    Creator:
    Prasertpalichat, Sasiporn
    Abstract:
    The role of A-site non-stoichiometry was investigated in lead-free piezoelectric ceramics based on compositions in the 1-x(Bi₀.₅Na₀.₅TiO₃)-xBaTiO₃ system near the morphotropic phase boundary where x = 0.055, 0.06 and 0.07. The samples were prepared by a conventional solid state mixed oxide route with the A- site stoichiometry modified to incorporate...
    Resource Type:
    Dissertation
    Full Text:
    ) Idealized S-E hysteresis loop from monodomain single crystal which assume prompt switching of polarization

  • Substitutional Effects on the Electromechanical Properties of Lead-free, Piezoelectric (Na₀.₅Bi₀.₅)TiO₃-BaTiO₃ (NBT-BT)

    Creator:
    McQuade, Ryan R.
    Abstract:
    This work investigates the effect of cation substitution on the properties of the lead-free, solid solution (Na₀.₅Bi₀.₅)TiO₃-BaTiO₃ (NBT-BT). Substitution into NBT-BT increases disorder and increases the relaxor ferroelectric properties. These relaxor ferroelectric materials show large piezoelectric strains that can be utilized in actuator applications. Ceramic samples were prepared using standard...
    Resource Type:
    Dissertation
    Full Text:
    . Waser……………………………………………………………………….48 Figure 1.29: a) Idealized bipolar strain vs. electric field (S

  • Defect Mechanisms in Bismuth-based Perovskites

    Creator:
    Kumar, Nitish
    Abstract:
    The aim of this research is to develop a fundamental understanding of the dominant defect species and the relevant defect equilibrium conditions for bismuth-containing perovskites to help guide the development of these materials for emerging applications. This is of paramount importance for many demanding applications, because ultimately the defect equilibria...
    Resource Type:
    Dissertation
    Full Text:
    ………………………………………………………………………………..……. 176 9.6.1 X-ray diffraction patterns of as-sintered stoichiometric (S), barium deficient (Ba def