Index Catalog // ScholarsArchive@OSU

Evaluation of Cycling Behavior: Factors that Influence Bicyclists’ Comprehension, Comfort, and Stress

Creator:: Cobb, Douglas P.
Abstract:: Travel demand has increased due to population growth, increase of vehicle ownership, and development patterns resulting in greater levels of congestion, pollution, and crash frequency. One approach to demand management is to increase the share of trips made by bicycles. With the increase in bicycling rates, there is a critical...
Resource Type:: Dissertation
Full Text:: SYSTEMS Douglas Cobb, Hisham Jashami, Christopher Monsere, Sirisha Kothuri, Amy Wyman, and David S

Sound and Vibration Analysis of Alternative Rumble Strips

Creator:: Horne, Dylan Ross
Abstract:: Roadway departure crashes accounted for 18,275 fatal crashes in 2017 across the United States (Jones et al. 2017). Rumble strips (RS) provide audible and haptic interior alert when a vehicle is departing the roadway reducing run-off-the road crashes. Although inexpensive to install, and easy to maintain, RS are not installed...
Resource Type:: Dissertation
Full Text:: in the writing process. Christopher M. Monsere, and Sirisha Kothuri provided valuable input on the

Plants and their Environment: Assessing Canopy Microclimate and the Response of Trees to Environmental Stress in a Diversity of Forest Types

Creator:: Sibley, Adam M.
Abstract:: The topics in this dissertation are centered around the way that trees respond to environmental stress in the climates where they occur. Though forests across the planet are expected to experience change in local climate due to historic and ongoing anthropogenic greenhouse gas emissions, the effects of climate change will...
Resource Type:: Dissertation
Full Text:: AN ABSTRACT OF THE DISSERTATION OF Adam M

Conformationally chiral diphenylethers and the enantioselective Ullmann etherification

Creator:: Salih, M. Quamar
Abstract:: Since the discovery of molecular chirality in 1848, this notion has had a substantial impact on medicine, biology, and chemistry. Extensive effort has been directed towards the construction of chiral molecules that contain sp³ hybridized stereogenic centers. In contrast, less effort has been dedicated to molecules that are chiral by...
Resource Type:: Dissertation
Full Text:: !DISSERTATION!OF! ! M.!Quamar!Salih!for!the!degree!of!Doctor!of!Philosophy!in!Chemistry!presented!on! May!1

The development of aminal radicals for the synthesis of nitrogen-rich natural products

Creator:: Schiedler, David A.
Abstract:: Organic compounds which contain one or more nitrogen atoms are especially important as they are disproportionately represented among biologically active molecules. As a result, significant effort has been focused on the development of methods for the synthesis of nitrogenous molecules. We identified the aminal as an under-explored functional group. Despite...
Resource Type:: Dissertation
Full Text:: . Abstract approved: ______________________________________________________ Christopher M. Beaudry

Total Synthesis of Aspidosperma Alkaloids Leuconoxine, Melodinine E and Mersicarpine and Synthetic Studies directed toward the Iboga Alkaloid Ibogaine: Progress directed toward the dimeric Cephalotaxus Alkaloid Cephalancetine C

Creator:: Kim, GilSoo
Abstract:: The first part of this manuscript is about the total synthesis of the aspidosperma alkaloids leuconoxine, melodinine E and mersicarpine. Our synthetic strategy used a radical translocation-conjugate addition cascade to construct the core of the natural product. Specifically, a vinyl radical was generated from the homolysis of the C–I bond...
Resource Type:: Dissertation
Full Text:: : ______________________________________________________ Christopher M. Beaudry The first part of this manuscript is about the total synthesis of the

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

Creator:: Vellucci, Jessica K.
Abstract:: Aminal radical intermediates were generated by the method of radical translocation and reacted in C-C bond forming reactions with electronically deficient alkenes (Schiedler et al. Org. Lett. 2012, 14, 6092). Aminal radical intermediates can participate in inter- and intra-molecular reactions using both Bu3SnH and (TMS)₃SiH as hydride donors. Carbon–carbon bonds...
Resource Type:: Dissertation
Full Text:: : ______________________________________________________ Christopher M. Beaudry Aminal radical intermediates were generated by the method of

Total Synthesis of Cephalotaxus Alkaloids and Synthetic Studies toward Bazzanin K

Creator:: Ju, Xuan
Abstract:: Dearomatization reactions exist broadly in biosynthesis and chemical synthesis. The highly functionalized atoms of arenes can be masked by it aromaticity, and upon dearomatization, those reactive atoms can be readily applied to bond formation and further manipulation. The total synthesis of (–)-cephalotaxine and (–)- homoharringtonine is described via an oxidative...
Resource Type:: Dissertation
Full Text:: : ______________________________________________________ Christopher M. Beaudry Dearomatization reactions exist broadly in biosynthesis and chemical

Regioselective Synthesis of Substituted Phenols, Benzenes, Benzofuranones and Benzofurans and Synthesis of Homoharringtonine Analogs

Creator:: Zhang, Xiaojie
Abstract:: Substituted phenols are important substructures for pharmaceuticals, agrochemicals, natural products and biological probe molecules. The properties of phenolic molecules are substantially influenced by the substitution patterns of the phenolic ring. The chemical synthesis of phenols with various substitution patterns is an enduring challenge and multiple strategies have emerged. However, some...
Resource Type:: Dissertation

Strategies for the Synthesis of Nitrogeous Compounds : Aminal Radical Reaction and Pyridinium Oxide Cycloadditions

Creator:: Lu, Yi
Abstract:: Pharmaceuticals, molecular catalysts, and secondary metabolites often contain nitrogen. The problems faced synthesizing compounds which contain nitrogen was because of the Lewis base reactivity of nitrogen lone pairs, and the acidic protons of some nitrogenous functional groups. We developed two methods for the synthesis of nitrogeous compounds. Additionally, we successfully...
Resource Type:: Dissertation

ScholarsArchive@OSU

Evaluation of Cycling Behavior: Factors that Influence Bicyclists’ Comprehension, Comfort, and Stress

Sound and Vibration Analysis of Alternative Rumble Strips

Plants and their Environment: Assessing Canopy Microclimate and the Response of Trees to Environmental Stress in a Diversity of Forest Types

Conformationally chiral diphenylethers and the enantioselective Ullmann etherification

The development of aminal radicals for the synthesis of nitrogen-rich natural products

Total Synthesis of Aspidosperma Alkaloids Leuconoxine, Melodinine E and Mersicarpine and Synthetic Studies directed toward the Iboga Alkaloid Ibogaine: Progress directed toward the dimeric Cephalotaxus Alkaloid Cephalancetine C

Total Synthesis of Goniomitine : Development of Aminal and α-Amino Radicals in the Synthesis of Nitrogen-Rich Natural Products

Total Synthesis of Cephalotaxus Alkaloids and Synthetic Studies toward Bazzanin K

Regioselective Synthesis of Substituted Phenols, Benzenes, Benzofuranones and Benzofurans and Synthesis of Homoharringtonine Analogs

Strategies for the Synthesis of Nitrogeous Compounds : Aminal Radical Reaction and Pyridinium Oxide Cycloadditions

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