An interlaboratory study of Mg/Ca and Sr/Ca ratios in three commercially available carbonate reference
materials (BAM RS3, CMSI 1767, and ECRM 752-1) was performed with the participation of
25 laboratories that determine foraminiferal Mg/Ca ratios worldwide. These reference materials containing
Mg/Ca in the range of foraminiferal calcite (0.8 mmol/mol to...
Boreal summer insolation during the last interglaciation (LIG) generally warmed the subpolar to polar Northern Hemisphere more than during the early Holocene, yet regional climate variations between the two periods remain. We investigate northeast Labrador Sea subsurface temperature and hydrography across terminations (T) I and II and during the LIG...
Mg/Ca ratios in planktonic foraminifera reflect calcification temperatures and are thus useful for sea
surface temperature (SST) reconstructions. Despite the obvious utility of this paleoceanographic tracer,
problems of dissolution, gametogenic calcification, and contaminant phases have thus far limited
confidence in Mg/Ca-based reconstructions. Here we show strong evidence of Mg heterogeneity...
Isotopic analyses of dissolved molybdenum are presented for sediment pore waters from a reducing
sedimentary basin and for fluids from a low-temperature ridge flank hydrothermal system. δ⁹⁸/⁹⁵Mo in
these fluids range from 0.8 to 3.5%₀ (relative to a laboratory standard), demonstrating that marine
sedimentary reactions significantly fractionate Mo isotopes. Within...
Measurements of the U₃₇ K’ index and the absolute abundance of alkenones in marine sediments are increasingly used in paleoceanographic research as proxies of past sea surface
temperature and haptophyte (mainly coccolith-bearing species) primary productivity, respectively. An
important aspect of these studies is to be able to compare reliably data...
Understanding the frequency, magnitude, and nature of explosive volcanic eruptions is essential for hazard planning and risk mitigation. Terrestrial stratigraphic tephra records can be patchy and incomplete due to subsequent erosion and burial processes. In contrast, the marine sedimentary record commonly preserves a more complete historical record of volcanic activity...
We present concentrations of germanium and silicon in sediment pore waters, basaltic formation fluids,
and bulk sediment from three ridge flank hydrothermal systems (RFHS). Basaltic formation fluids from
warm (>30°C) RFHS have much higher Ge concentrations and Ge:Si molar ratios than overlying sediment
pore waters, requiring seawater-basalt reactions to dominate...
The rare earth elements (REEs) with their systematically varying properties are powerful tracers of continental inputs, particle scavenging intensity and the oxidation state of seawater. However, their generally low (similar to pmol/kg) concentrations in seawater and fractionation potential during chemical treatment makes them difficult to measure. Here we report a...
Glacial sedimentary sequences in the north central United States record multiple advances of the
Laurentide Ice Sheet (LIS) since ~2 Ma. Although the tills found in these sequences were deposited by
southward flowing glacial lobes, little information is available on the geometry of flow lines in the interior
of the...
Marine sediments around volcanic islands contain an archive of volcaniclastic deposits, which can be used to reconstruct the volcanic history of an area. Such records hold many advantages over often incomplete terrestrial data sets. This includes the potential for precise and continuous dating of intervening sediment packages, which allow a...