High-resolution infrared absorption spectra have been analyzed for two bicyclo[111]pentane isotopologues, C₅H₈ (-d₀) and C₅H₇D (-d₁), where in the latter the D-atom replaces a hydrogen on the C₃ symmetry axis such that the molecular symmetry is reduced from D₃ₕ to C₃ᵥ. Two (a"₂) parallel bands, v₁₇ and v₁₈, of bicyclopentane-d₀...
Simultaneous measurements of vertical velocity fluctuations, w′, and temperature fluctuations, T′, on scales of three-dimensional turbulence yield a direct measure of the turbulent heat flux, J[subscript]q. The scales contributing most significantly to J[subscript]q are tens of centimeters or about 10 times larger than the scales contributing to the turbulent kinetic...
As a quantitative test of moored mixing measurements using [subscript χ]pods, a comparison experiment was conducted at 0°, 140°W in October–November 2008. The following three measurement elements were involved: (i) NOAA’s Tropical Atmosphere Ocean (TAO) mooring with five [subscript χ]pods, (ii) a similar mooring 9 km away with seven [subscript...
The decay of a downward propagating near-inertial wave was observed over four days. During this short period, the energy of the near-inertial wave decreased by 70%. The shear layers produced by the wave were regions of enhanced turbulent dissipation rates. The authors estimate that 44% of the observed change in...
A detailed investigation of the upper ocean during convection reveals
1.
• the vertical structure of potential temperature, θ, to be steady in time, and
2.
• the current shear to vanish in the bulk of the mixed layer.
These imply that a “slab”-type model may be an adequate representation...
Clear identification of the relatively weak superadiabatic potential temperature gradient in the ocean surface layer during convection has been made with the help of intensive vertical profiling measurements at an open-ocean site. In the surface layer the superadiabatic gradient, with a mean value of −1.8 × 10⁻⁴ K m⁻¹, was...
A freely rising profiler was used to collect vertical microstructure profiles in the upper oceanic boundary layer under various atmospheric and sea conditions. Near the sea surface, the rate of viscous dissipation of turbulence kinetic energy, ϵ, exhibited a range of behaviors under different forcing conditions. Sometimes, ϵ was closely...
Recent turbulence measurements over a small bank on the continental shelf off Oregon reveal a previously undetected site for intense mixing of the coastal ocean. The flow is hydraulically controlled and turbulence diffusivities over the bank are more than 100 times greater than estimates made on the shelf away from...
Highly resolved pressure measurements on the seafloor over New Jersey’s continental shelf reveal the pressure signature of nonlinear internal waves of depression as negative pressure perturbations. The sign of the perturbation is determined by the dominance of the internal hydrostatic pressure (p⁰Wh) due to isopycnal displacement over the contributions of...